Hostname: page-component-76fb5796d-r6qrq Total loading time: 0 Render date: 2024-04-26T22:13:29.451Z Has data issue: false hasContentIssue false
  • English
  • Français

Determination of Crystal Structure of Cd3(BO3)2 by Powder X-Ray Diffraction

Published online by Cambridge University Press:  10 January 2013

Y. Laureiro ,
M.L. Veiga ,
M.L. López ,
S. García-Martín ,
A. Jerez  and
C. Pico
Y. Laureiro
Affiliation:
Departemento de Química Inorgánica I, Facultad Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain
M.L. Veiga
Affiliation:
Departemento de Química Inorgánica I, Facultad Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain
M.L. López
Affiliation:
Departemento de Química Inorgánica I, Facultad Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain
S. García-Martín
Affiliation:
Departemento de Química Inorgánica I, Facultad Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain
A. Jerez
Affiliation:
Departemento de Química Inorgánica I, Facultad Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain
C. Pico
Affiliation:
Departemento de Química Inorgánica I, Facultad Ciencias Químicas, Universidad Complutense, 28040 Madrid, Spain
Get access Rights & Permissions [Opens in a new window]

Abstract

Cd3(BO3)2 was prepared by a solid state reaction between B(OH)3 and Cd(OH)2 at low temperatures ranging between 523° and 623° and at a pressure of 10−4 – 10−5 Hg mm. The crystal structure has been refined by Rietveld analysis of X-ray powder diffraction data. The compound crystallizes in the orthorhombic system, space group Pnnm, Z = 2, with cell parameters of a = 5.967(5) Å, b = 4.78 (0) Å and c = 9.009(5) Å.

Type
Research Article
Information
Powder Diffraction , Volume 6 , Issue 1 , March 1991 , pp. 28 - 30
Copyright
Copyright © Cambridge University Press 1991

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Abrahams, S.C., Bernstein, J.L. & Keve, E.T. (1977). J. Appl. Crystallogr. 4, 284.CrossRefGoogle Scholar
Berger, S.V. (1949). Acta Chem. Scand. 3, 660.CrossRefGoogle Scholar
Bohlhoff, R., Bambauer, H.V. & Hoffman, W. (1971). Z Kristallogr. 133, 386.CrossRefGoogle Scholar
Christ, C.L. & Clark, J.R. (1977). Phys. Chem. Miner. 2, 59.CrossRefGoogle Scholar
Farmer, J.B. (1982). Advances in Inorg. Chem. and Radiochem. 25, 187.Google Scholar
García-Blanco, S. & Fayos, J. (1968). Z Kristallogr. 127, 145.CrossRefGoogle Scholar
Hart, P.B. & Steward, E.G. (1962). J. Inorg. Nucl. Chem. 24, 633.CrossRefGoogle Scholar
Jansen, M. & Scheld, W. (1981). Z Anorg. Allg. Chem. 477, 85.CrossRefGoogle Scholar
Laureiro, Y., Jerez, A., & Pico, C. (1988). Synth. Reac. Met. Org. Chem. 18(2), 119.CrossRefGoogle Scholar
Laureiro, Y., Veíga, M.L., & Pico, C. (1989). Il Symposium of Crystallographic Group of RSEFQ. Castellon, Spain.Google Scholar
Laureiro, Y., Veiga, M.L., Fernández, F., Saez-Puche, R., Jerez, A., & Pico, C. (1990). J. Less Common Met. 157, 335.CrossRefGoogle Scholar
Pardo, J., Martinez-Ripoll, M., & García-Blanco, S. (1074). Acta Crystallogr. B30, 37.Google Scholar
Rodriquez-Carvajal, J. (1990), Program Fullprof. ILL, Grenoble, France.Google Scholar
Shannon, R.D. (1976). Acta Crystallogr. A32, 751.CrossRefGoogle Scholar
Stewner, F. (1971). Acta Crystallogr. B27, 904.CrossRefGoogle Scholar
Vegas, A., Cano, F.H., & García-Blanco, S. (1975). Acta Crystallogr. B31, 1416.CrossRefGoogle Scholar