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Cu K-edge XANES: polymer, organic, inorganic spectra, and experimental considerations

Published online by Cambridge University Press:  27 July 2017

Mikael Larsson ,
Johan B. Lindén ,
Simarpreet Kaur ,
Brock Le Cerf  and
Ivan Kempson
Mikael Larsson
Affiliation:
University College London, School of Energy and Resources, 220 Victoria Square, Adelaide, SA 5000, Australia Future Industries Institute, University of South Australia, Mawson Lakes, SA 5095, Australia
Johan B. Lindén
Affiliation:
Future Industries Institute, University of South Australia, Mawson Lakes, SA 5095, Australia Research Institutes of Sweden, Division of Bioscience and Materials, Chemistry, Materials and Surfaces, Brinellgatan 4, 50462, Borås, Sweden
Simarpreet Kaur
Affiliation:
Future Industries Institute, University of South Australia, Mawson Lakes, SA 5095, Australia
Brock Le Cerf
Affiliation:
Future Industries Institute, University of South Australia, Mawson Lakes, SA 5095, Australia
Ivan Kempson*
Affiliation:
Future Industries Institute, University of South Australia, Mawson Lakes, SA 5095, Australia
*
a)Author to whom correspondence should be addressed. Electronic mail: Ivan.Kempson@unisa.edu.au
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Abstract

In pursuit of design and characterisation of Cu adsorbing in thin films, we present data from a large variety of Cu-K edge X-ray Absorption Near Edge Spectroscopy (XANES) spectra obtained from organic and inorganic standards. Additionally, we have explored the impact of beam damage inducing redox alterations. Polymer nanoparticles were tested against films to produce higher concentration samples while maintaining high surface area to bulk effects. Spectra from nanoparticles were highly comparable to thin films of ~8 nm thickness, implying comparable contributions by surface effects on copper association. Finally, we observed no impact on Cu XANES spectra from vitrification with dimethyl sulfoxide to produce amorphous frozen, hydrated samples. The spectra should act as a valuable resource in assisting the design of experiments and identification of copper associations.

Keywords

Cu-K edge XANESthin filmsnanoparticlespolymersanti-biofouling
Type
Technical Articles
Information
Powder Diffraction , Volume 32 , Supplement S2 , December 2017 , pp. S28 - S32
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Copyright
Copyright © International Centre for Diffraction Data 2017 

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