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Crystal and powder neutron diffraction data of Tl3Li(MO4)2 (M=Mo, W)

Published online by Cambridge University Press:  10 January 2013

A. M. Xuriguera
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
C. Colbeau Justin
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
A. Elfakir
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
M. Quarton
Affiliation:
Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France

Abstract

Two structurally related compounds, Tl3Li(MoO4)2 and Tl3Li(WO4)2, have been synthesized by solid state reaction. Space group (P63mc) and unit-cell parameters [a(Å)=6.00392(3); c(Å)=15.8203(1) and a(Å)=6.03484(3); c(Å)=15.81759(9), respectively, for Tl3Li(MoO4)2 and Tl3Li(WO4)2] were determined. Powder diffraction data for each phase are reported.

Type
Research Article
Copyright
Copyright © Cambridge University Press 1998

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References

Blum, D., Durif, A., and Averbuch-Pouchot, M. T. (1986). “Crystal structures of the three forms of cesium zinc phosphate: CsZnPO4,” Ferroelectrics 69, 283292.CrossRefGoogle Scholar
Colbeau-Justin, C., Souron, J. P., Elfakir, A., and Quarton, M. (1993). Proceedings of “Journées d’Etudes de la SEE, Matériaux piézo-pyro-ferroélectriques et leurs applications,” P1F, Limoges, France.Google Scholar
Colbeau-Justin, C., Wallez, G., Xuriguera, A. M., Elfakir, A., Jaulmes, S., and Quarton, M. (1997). “Structure determination of Tl 3Li(MoO 4)2. Stereochemical activity of thallium (I) lone pair,” Eur. J. Solid State Inorg. Chem. 34, 10971106.Google Scholar
De Wolff, P. M. (1968). “A simplified criterion for the reliability of powder-pattern indexing,” J. Appl. Crystallogr. 1, 108109.CrossRefGoogle Scholar
Elouadi, B., Elammari, L., and Ravez, J. (1984). “A new ferroelectric phosphate family,” Ferroelectrics 56, 1720.CrossRefGoogle Scholar
Jaulmes, S., Wallez, G., Elfakir, A., and Quarton, M. (1993). “Crystal and structure determination of the monoarsenate CsBeAsO 4,Eur. J. Solid State Inorg. Chem. 30, 10071015.Google Scholar
Klevtsvo, P. (1988). J.C.P.D.F. Files: 44-627 and 44-628.Google Scholar
Masse, R., and Durif, A. (1988). “Contribution to the crystal chemistry of M M PO 4 monophosphates,” J. Solid State Chem. 73, 468.CrossRefGoogle Scholar
Mighell, A. D., Hubbard, G. R., and Stalick, J. K. (1981). “NBS* AIDS 83, is a development of “NBS* AIDS 80, “A FORTRAN Program for Crystallographic Data Evaluation,” Nat. Bur. Stand. (U.S.) Tech. Note 1141.Google Scholar
Mokhosoev, M. V., Arkhincheeva, S. I., Bazarova, Z. G., Khazheeva, Z. I., and Munkueva, S. D. (1989). “Phase equilibria in the Tl 2MoO 4-Li 2MoO 4-MoO 3 and Tl 2MoO 4-Na 2MoO 4-MoO 3 systems,” Russ. J. Inorg. Chem. (Engl. Trans.) 34, 738741.Google Scholar
Okada, O. (1981). J.C.P.D.F. Files: 34-84 and 34-85.Google Scholar
Smith, G. J., and Snyder, R. L. (1979). “F N: A criterion for rating powder diffraction patterns and evaluation the reliability of powder-pattern indexing,” J. Appl. Crystallogr. 12, 6065.CrossRefGoogle Scholar
Wallez, G., Jaulmes, S., Elfakir, A., and Quarton, M. (1994). “Un nouveau phosphate ferroélectrique,” J. Phys. III 4, 11971204.Google Scholar
Wallez, G., Jaulmes, S., Elfakir, A., and Quarton, M. (1995). “Stereochemical Activity of Thallium (I) Lone pair in the tridymite-Related compounds TlBePO 4 and TlBeAsO 4,J. Solid State Chem. 114, 123128.CrossRefGoogle Scholar