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X-Ray Diffraction Study of Cubic Boron Nitride Grown Epitaxially on Silicon

Published online by Cambridge University Press:  25 February 2011

G. L. Doll
Affiliation:
General Motors Research Laboratories, 30500 Mound Road, Warren, MI 48090
J. A. Sell
Affiliation:
General Motors Research Laboratories, 30500 Mound Road, Warren, MI 48090
A. Wims
Affiliation:
General Motors Research Laboratories, 30500 Mound Road, Warren, MI 48090
C. A. Taylor
Affiliation:
Physics Department, University of Michigan, Ann Arbor, MI 48109
R. Clarke
Affiliation:
Physics Department, University of Michigan, Ann Arbor, MI 48109
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Abstract

We report the growth of boron nitride films on (001), (110), and (111) faces of silicon using the method of pulsed excimer laser ablation. The structure of the Alms grown on the (001) and (110) orientations of Si is cubic zincblende with a lattice constant of 3.619 Å. The films were found to be heteroepitaxial on silicon (001) with the cubic BN (100) axes parallel to Si (100), as characterized by x-ray diffraction and high-resolution transmission electron microscopy. In that system, we find evidence for an unusual 3:2 commensurate lattice matching. The films appear to cubic but randomly oriented on the Si (110), and no evidence for crystallinity is found for films grown on Si (111).

Type
Research Article
Copyright
Copyright © Materials Research Society 1991

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References

REFERENCES

[1] Doll, G. L., Sell, J. A., Salamanca-Riba, L., and Ballal, A. K., in Laser Ablation for Materials Synthesis, edited by Paine, D. C. and Bravman, J. C. (Mater. Res. Soc. Proc. 191, Pittsburgh, PA 1990) pp. 5560.Google Scholar
[2] Bauer, E. G., Dodson, B. W., Ehrlich, D. J., Feldman, L. C., Flynn, C. P., Geis, M. W., Harbison, J. P., Matyi, R. J., Peercy, P. S., Petroff, P. M., Phillips, J. M., Stringfellow, G. B., and Zangwill, A., J. Mat. Res. 5, 852 (1990).Google Scholar
[3] Koizumi, S., Murakami, T., Inuzuka, T., and Suzuki, K., Appl. Phys. Lett. 57, 563 (1990).Google Scholar
[4] Arya, S. P. S. and D’Amico, A., Thin Solid Films 157, 267 (1988).Google Scholar
[5] Kessler, G., Bauer, H.-D., Pompe, W., and Scheibe, H.-J., Thin Solid Films 147, L45 (1987).Google Scholar
[6] Murray, P.T, Donley, M.S, and McDevitt, N.T, in Processing and Characterization of Materials Using Jon Beams, edited by Rehn, L.E, Greene, J.E, and Smidt, F.A (Materials Res. Soc. Proc. 128, Pittsburgh, PA 1989) p. 469.Google Scholar
[7] Sankur, H. and Cheung, J. T., Appl. Phys. A 47, 271 (1988).Google Scholar
[8] Pyrolytic boron nitride targets were obtained from Union Carbide Coatings Service Corporation, 11907 Madison Avenue, Cleveland, OH 44107.Google Scholar
[9] Higashi, G. S., Chabal, Y. J., Trucks, G. W., and Raghavachari, K., Appl. Phys. Lett. 56, 656 (1990).Google Scholar
[10] The ablation threshold for hBN was determined in a separate experiment to be between 0.31 and 0.34 J/cm2; Sell, J.A, Doll, G.L, and Heffelfinger, D.M (unpublished).Google Scholar
[11] JCPDS Powder Diffraction File 25–1033.Google Scholar
[12] Cullity, B. D., Elements of X-ray Diffraction 2nd Edition, (Addison-Wesley, Reading, Massachusetts, 1978), p. 142.Google Scholar
[13] Sheftal, R. N. and Cherbakov, I. V., Crys. Res. Techn. 16, 887 (1981).Google Scholar