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Transport Properties and Lithium Insertion of Compounds Metal-Halogen-Chalcogenides

Published online by Cambridge University Press:  28 February 2011

C. Julien ,
L. El-Farh ,
I. Samaras ,
I. Riess ,
M. Balkanski ,
S. Ziolkiewicz  and
A. Chevy
C. Julien
Affiliation:
Laboratoire de Physique des Solides, associé au CNRSUniversité P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
L. El-Farh
Affiliation:
Laboratoire de Physique des Solides, associé au CNRSUniversité P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
I. Samaras
Affiliation:
Laboratoire de Physique des Solides, associé au CNRSUniversité P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
I. Riess
Affiliation:
Laboratoire de Physique des Solides, associé au CNRSUniversité P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
M. Balkanski
Affiliation:
Laboratoire de Physique des Solides, associé au CNRSUniversité P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
S. Ziolkiewicz
Affiliation:
Laboratoire d'Optique de la Matière Condensée et Ultrasons, associé au CNRSUniversité P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
A. Chevy
Affiliation:
Laboratoire de Physique des Milieux Condensés, associé au CNRSUniversité P. et M. Curie, 4 place Jussieu, 75252 Paris Cedex 05, France
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Abstract

The transport properties and far-infrared reflectivity of BiSI, BiTel, SbTeI, Bi2 Se3 and Bi2S3 have been studied, and the results show a good agreement between the two techniques. Lithium insertion within metal-chalcogen-halogen compounds has been carried out using Li/LiC1O4-PC/MChI galvanic cells at room temperature. Electrochemical potential spectroscopy measurements show the different regimes involved in the insertion reaction.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 210: Symposium L – Solid State Ionics II , 1990 , 461
Copyright
Copyright © Materials Research Society 1991

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