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Thin Films of Ionic Conductors by Laser Ablation

Published online by Cambridge University Press:  10 February 2011

M. Morcrette ,
P. Barboux ,
J. Perrière ,
A. Laurent ,
J. P. Boilot  and
T. Brousse
M. Morcrette
Affiliation:
Physique de la Matière Condensée, Ecole Polytechnique, 91128 Palaiseau, France Groupe de Physique des Solides, Université Pierre et Marie Curie, 4 Place Jussieu, 75251 Paris, France
P. Barboux
Affiliation:
Physique de la Matière Condensée, Ecole Polytechnique, 91128 Palaiseau, France
J. Perrière
Affiliation:
Groupe de Physique des Solides, Université Pierre et Marie Curie, 4 Place Jussieu, 75251 Paris, France
A. Laurent
Affiliation:
Groupe de Physique des Solides, Université Pierre et Marie Curie, 4 Place Jussieu, 75251 Paris, France
J. P. Boilot
Affiliation:
Physique de la Matière Condensée, Ecole Polytechnique, 91128 Palaiseau, France
T. Brousse
Affiliation:
Laboratoire de Génie des Matériaux, ISITEM, Rue Christian Pauc, BP 90604, 44306 Nantes Cedex 3, Francephilippe.barboux@polytechnique.fr
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Abstract

Films of insertion compounds and solid state electrolytes have been synthesized in order to study their applications in the domain of electrochemical ion and gas sensors. Laser ablation was used to deposit lithium metal oxides (LiMO2 where M is a transition metal Co or Mn).

The chemical composition in the films has been studied by Rutherford Backscattering spectrometry and nuclear reactions analysis in the case of the light elements (O, Li). For lithium transition metal oxides (LiMO2), the oxygen and lithium contents are determined by a thermodynamical equilibrium between the films and the partial pressures in the chamber. In these cases, laser ablation allows the synthesis of crystalline structures with a large range of oxygen non stoichiometry as compared to solid state reactions. They lead to interesting electrical properties. Using the appropriate temperatures and oxygen pressures, films with the correct stoichiometry could be obtained as polycrystalline onto Si or Si/Pt substrates whereas they exhibit high texturing and epitaxial growth onto MgO or MgO/Pt.

The films of LiMn2O4 and LiCoO2 have been used as electrochemical sensors for the measurement of the lithium concentration in solutions. They show a very rapid and selective response.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 548: Symposia EE – Solid State Ionics V , 1998 , 213
Copyright
Copyright © Materials Research Society 1999

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References

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