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Thickness Effect On The Crystallization Kinetics Of Electrolessly-Deposited Ni(P) Thin Films

Published online by Cambridge University Press:  15 February 2011

L. T. Shi
Affiliation:
IBM Thomas J.Watson Research Center, Yorktown Heights, NY 10598
E. J. M. O'Sullivan
Affiliation:
IBM Thomas J.Watson Research Center, Yorktown Heights, NY 10598
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Abstract

In order to understand thickness and interfacial effects on the crystallization kinetics of amorphous solids, Ni(P) thin films electrolessly deposited on Cu seed layers were annealed at constant heating rates or at constant temperatures in a DSC to obtain activation energies andAvrami exponents. It was found that the activation energy of crystallization in Ni(P) changes asa function of sample thickness when the sample thickness is less than 1.0 μm. Furthermore, the Avrami exponent was found to change not only as a function of thickness but also as a function of annealing temperature.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

1. Grewal, M.S., Sastri, S.A., and Alexander, B.H., Thermochimica Acta, 14, 25 (1976).Google Scholar
2. Mahoney, M.W. and Dynes, P.J., Scripta Metall., 19, 539 (1985).Google Scholar
3. Bakonyi, I., Cziraki, A., Nagy, I. and Hosso, M., Z.Metallkd., 77, 425 (1986).Google Scholar
4. Ma, E., Lu, S., and Li, P., Thin Solid Films, 166, 273 (1988).Google Scholar
5. Szasz, A., Pan, X.D., Kojnok, J., and Fabian, D.J., J. Non-Cryst. Solids, 108, 304 (1989).Google Scholar
6. Lin, K.L. and Lai, P.J., J. Electrochem. Soc., 136, 3803 (1989).Google Scholar
7. Agarwala, R.C. and Ray, S., Z.Metallkd., 80, 556 (1989).Google Scholar
8. Agarwala, R.C. and Ray, S., Z.Metallkd., 83, 203 (1992).Google Scholar
9. Graham, A.H., Lindsay, R.W., and Read, H.J., J. Electrochem. Soc., 112, 401 (1965).Google Scholar
10. Randin, J.P., Maire, P.A., Saurer, E., and Hintermann, H.E., J. Electrochem. Soc., 114, 442 (1967).Google Scholar
11. Kissinger, H.E., Anal. Chem., 29, 1702 (1957).Google Scholar
12. Ozawa, T., J.Thermal Analysis, 2, 301 (1970).Google Scholar
13. Ma, E. and Thompson, C.V., J. Appl. Phys., 69, 2211 (1991).Google Scholar
14. Tu, K.N., Appl. Phys. A, 53, 32 (1991).Google Scholar
15. Christian, J.W., The Theory of Transformation in metals and Alloys, 2nd ed. (Pergamon, Oxford, 1975).Google Scholar