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Thermal Stability of Structurally Controlled Lamellae and Hexagonal Mesoporous Silicate Thin Films

Published online by Cambridge University Press:  10 February 2011

I. Honma ,
A. Endo ,
D. Kundu  and
H. S. Zhou
I. Honma
Affiliation:
Energy division, Electrotechnical Laboratory, AIST, Umezono 1–1-4, Tsukuba, Ibaraki,305, Japan, ihonma@etl.go.jp, tel:+81–298–54–5797, fax:+81–298–54–5805
A. Endo
Affiliation:
National Institute of Materials and Chemical Research, AIST, Tsukuba, Ibaraki, Japan
D. Kundu
Affiliation:
Sol-Gel Division, Central Glass and Ceramic Research Institute, Calcutta, India.
H. S. Zhou
Affiliation:
Energy division, Electrotechnical Laboratory, AIST, Umezono 1–1-4, Tsukuba, Ibaraki,305, Japan, ihonma@etl.go.jp, tel:+81–298–54–5797, fax:+81–298–54–5805
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Abstract

Thin films of mesoporous materials have been synthesized recently as lamellar, one dimensional hexagonal and cubic structures at substrate surfaces as well as at air/liquid interfaces. The present work investigates thermally induced structural changes of lamellar and one-dimensional hexagonal(1-dH) mesostructured silicate thin films, which is less known at the moment. The 1-dH films proved to be much more thermally stable than the lamellar ones; Open-pore one dimensionalhexagonalmesoporous thin films are obtained by the calcination of the films, where as the lamellarphase has collapsed after the surfactants removal.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 235
Copyright
Copyright © Materials Research Society 1999

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References

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