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Thermal and elastic properties of Ge-Sb-Te based phase-change materials

Published online by Cambridge University Press:  08 July 2011

P. Zalden ,
C. Bichara ,
J. v. Eijk ,
R. P. Hermann ,
I. Sergueev ,
G. Bruns ,
S. Buller ,
W. Bensch ,
T. Matsunaga  and
N. Yamada
...Show all authors
P. Zalden
Affiliation:
I. Physikalisches Institut (IA), RWTH Aachen University, Aachen, Germany JARA-FIT, RWTH Aachen, 52056 Aachen, Germany
C. Bichara
Affiliation:
Centre Interdisciplinaire de Nanoscience de Marseille, CINaM – CNRS and Aix-Marseille University, Campus de Luminy, 13288 - Marseille - Cedex 9 - France
J. v. Eijk
Affiliation:
I. Physikalisches Institut (IA), RWTH Aachen University, Aachen, Germany JARA-FIT, RWTH Aachen, 52056 Aachen, Germany
R. P. Hermann
Affiliation:
Jülich Centre for Neutron Science JCNS and Peter Grünberg Institut PGI, JARA-FIT, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany Faculté des Sciences, Université de Liège, 4000 Liège, Belgium
I. Sergueev
Affiliation:
I. Physikalisches Institut (IA), RWTH Aachen University, Aachen, Germany
G. Bruns
Affiliation:
I. Physikalisches Institut (IA), RWTH Aachen University, Aachen, Germany JARA-FIT, RWTH Aachen, 52056 Aachen, Germany
S. Buller
Affiliation:
Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, 24098 Kiel, Germany
W. Bensch
Affiliation:
Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, 24098 Kiel, Germany
T. Matsunaga
Affiliation:
Materials Science and Analysis Technology Centre, Panasonic Corporation, 3-1-1 Yagumo-Nakamachi, Moriguchi, Osaka 570-8501, Japan Japan Synchrotron Radiation Research Institute, Hyogo, Japan
N. Yamada
Affiliation:
Japan Synchrotron Radiation Research Institute, Hyogo, Japan Digital & Network Technology Development Centre, Panasonic Corporation, Osaka, Japan
M. Wuttig
Affiliation:
I. Physikalisches Institut (IA), RWTH Aachen University, Aachen, Germany JARA-FIT, RWTH Aachen, 52056 Aachen, Germany
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Abstract

Phase-change materials undergo a change in bonding mechanism upon crystallization, which leads to pronounced modifications of the optical properties and is accompanied by an increase in average bond lengths as seen by extended x-ray absorption fine structure (EXAFS), neutron and x-ray diffraction. The reversible transition between a crystalline and an amorphous phase and its related property contrast are already employed in non-volatile data storage devices, such as rewritable optical discs and electronic memories. The crystalline phase of the prototypical material GeSb2Te4 is characterized by resonant bonding and pronounced disorder, which help to understand their optical and electrical properties, respectively. A change in bonding, however, should also affect the thermal properties, which will be addressed in this study. Based on EXAFS data analyses it will be shown that the thermal and static atomic displacements are larger in the meta-stable crystalline state. This indicates that the bonds become softer in the crystalline phase. At the same time, the bulk modulus increases upon crystallization. These observations are confirmed by the measured densities of phonon states (DPS), which reveal a vibrational softening of the optical modes upon crystallization. This demonstrates that the change of bonding upon crystallization in phase-change materials also has a profound impact on the lattice dynamics and the resulting thermal properties.

Keywords

thermal conductivitystructuralextended x-ray absorption fine structure(EXAFS)
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1338: Symposium R – Phase-Change Materials for Memory and Reconfigurable Electronics Applications , 2011 , mrss11-1338-r06-03
Copyright
Copyright © Materials Research Society 2011

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