Hostname: page-component-7479d7b7d-rvbq7 Total loading time: 0 Render date: 2024-07-08T08:04:37.817Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis of Nanosized Polymer Particles in Nonaqueous Emulsion

Published online by Cambridge University Press:  31 May 2013

Robert Dorresteijn ,
Robert Haschick ,
Kevin Müller ,
Markus Klapper  and
Klaus Müllen
Robert Dorresteijn
Affiliation:
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
Robert Haschick
Affiliation:
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
Kevin Müller
Affiliation:
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
Markus Klapper*
Affiliation:
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
Klaus Müllen
Affiliation:
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
*
*E-mail: klapper@mpip-mainz.mpg.de
Get access

Abstract

In nonaqueous emulsion, moisture-sensitive polymerizations are performed in order to generate nanoparticles, which are not accessible by common aqueous emulsion polymerization. A nonaqueous emulsion, consisting of two immiscible aprotic organic solvents, is stabilized by amphiphilic block copolymers, such as PIb-PEO or PIb-PMMA copolymer, and lead to formation of nanosized dispersed droplets. They act as dispersed “nanoreactors” for the one-step synthesis of poly(urethane) nanoparticles in a polyadditon reaction as well as poly(L-lactide) nanoparticles through ring-opening polymerization, catalyzed by a moisture-sensitive catalyst. The well-dispersed particles possess average diameters below 100 nm and have narrow size distributions owing to the long-term stability of the dispersed droplets in the continuous phase.

Keywords

nanoscalenanostructurepolymerization
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1546: Symposium L – Nanoparticle Manufacturing, Functionalization, Assembly and Integration , 2013 , mrss13-1546-l06-32
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Taylor, J., Winnik, M., JCT Res., 2004, 1, 163–190.Google Scholar
Schuman, T., Karlsson, A., Larsson, J., Wikström, M., Rigdahl, M., Prog. Org. Coat., 2005, 54, 360–371.CrossRefGoogle Scholar
Kawaguchi, T., Tsugane, A., Higashide, K., Endoh, H., Hasegawa, T., Kanno, H., Seki, T., Juni, K., Fukushima, S., Nakano, M., J. Pharm. Sci., 1992, 81, 508–512.CrossRefGoogle Scholar
Hatakeyama, M., Iwato, S., Hanashita, H., Nakamura, K., Fujimoto, K., Kawaguchi, H., Colloids Surf., A, 1999, 153, 445–451.CrossRefGoogle Scholar
Naundorf, C., Matsui, S., Saito, J., Fujita, T., Klapper, M., Müllen, K., J. Polym. Sci. A Polym. Chem., 2006, 44, 3103–3113.CrossRefGoogle Scholar
Klapper, M., Clark, C. G. Jr, Müllen, K., Polym. Int., 2008, 57, 181–202.CrossRefGoogle Scholar
Landfester, K., Willert, M., Antonietti, M., Macromolecules, 2000, 33, 2370–2376.CrossRefGoogle Scholar
Periard, J., Banderet, A., Riess, G., J. Polym. Sci. B Polym. Lett., 1970, 8, 109–114.CrossRefGoogle Scholar
Müller, K., Klapper, M., Müllen, K., Macromol. Rapid Commun., 2006, 27, 586–593.CrossRefGoogle Scholar
Klapper, M., Nenov, S., Haschick, R., Müller, K., Müllen, K., Acc. Chem. Res., 2008, 41, 1190–1201.CrossRefGoogle Scholar
Dorresteijn, R., Haschick, R., Klapper, M., Müllen, K., Macromol. Chem. Phys., 2012, 213, 1996–2002.CrossRefGoogle Scholar
Müller, K., Klapper, M., Müllen, K., Colloid Polym. Sci., 2007, 285, 1157–1161.CrossRefGoogle Scholar
Haschick, R., Klapper, M., Wagener, K. B., Müllen, K., Macromol. Chem. Phys., 2010, 211, 2547–2554.CrossRefGoogle Scholar
Karlsson, S., Albertsson, A.-c., Polym. Eng. Sci., 1998, 38, 1251–1253.CrossRefGoogle Scholar
Legrand, P., Lesieur, S., Bochot, A., Gref, R., Raatjes, W., Barratt, G., Vauthier, C., Int. J. Pharm., 2007, 344, 33–43.CrossRefGoogle Scholar
Ueda, M., Kreuter, J., J. Microencapsulation, 1997, 14, 593–605.CrossRefGoogle Scholar
Csihony, S., Culkin, D. A., Sentman, A. C., Dove, A. P., Waymouth, R. M., Hedrick, J. L., J. Am. Chem. Soc., 2005, 127, 9079–9084.CrossRefGoogle Scholar
Dechy-Cabaret, O., Martin-Vaca, B., Bourissou, D., Chem. Rev., 2004, 104, 6147–6176.CrossRefGoogle Scholar
Alves, P., Coelho, J. F. J., Haack, J., Rota, A., Bruinink, A., Gil, M. H., Eur. Polym. J., 2009, 45, 1412–1419.CrossRefGoogle Scholar