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Synthesis of luminescent nanoparticle embedded polymer nanocomposites for scintillation applications

Published online by Cambridge University Press:  28 January 2011

Thomas Rogers ,
Chenlu Han ,
Brent Wagner ,
Jason Nadler  and
Zhitao Kang
Thomas Rogers
Affiliation:
Georgia Tech Research Institute, Georgia Institute of Technology, 925 Dalney Street, Atlanta GA 30332-0826, U.S.A.
Chenlu Han
Affiliation:
Georgia Tech Research Institute, Georgia Institute of Technology, 925 Dalney Street, Atlanta GA 30332-0826, U.S.A.
Brent Wagner
Affiliation:
Georgia Tech Research Institute, Georgia Institute of Technology, 925 Dalney Street, Atlanta GA 30332-0826, U.S.A.
Jason Nadler
Affiliation:
Georgia Tech Research Institute, Georgia Institute of Technology, 925 Dalney Street, Atlanta GA 30332-0826, U.S.A.
Zhitao Kang*
Affiliation:
Georgia Tech Research Institute, Georgia Institute of Technology, 925 Dalney Street, Atlanta GA 30332-0826, U.S.A.
*
*Correspondence author. Email: zhitao.kang@gtri.gatech.edu.
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Abstract

Detecting gamma-ray emission from radionuclides hidden within containers is a significant concern to national security and can be accomplished with scintillating materials such as NaI:Tl, LaBr3:Ce crystals. However, the use of these high quality crystals limits the functionality of the detectors due to their high cost and scalability issues. Therefore the development of more durable, more easily manufactured, and more cost effective scintillating materials is desired. The incorporation of nanophosphors or Quantum Dots (QDs) into a polymer matrix to produce a transparent nanocomposite could potentially provide an alternative method to fabricate scintillating detectors. Embedded in a suitable polymer matrix, nanocomposite detectors may be easily made suitably large for portal monitors. Also, preparation of suitable particle sizes and/or compositions permits selection of a photon wavelength that optimally matches the photodetector response curve to increase the number of photons collected per pulse. In this paper a series of LaF3:Ce nanophosphors with varying doping concentrations (1–30mol%Ce) were synthesized using a chemical precipitation method. Photoluminescence and photoluminescence excitation characterizations indicated that the highest luminescent intensity was obtained from the 20%Ce doped sample with a peak emission at 325 nm. The refractive indices of the nanoparticles were identified by index matching measurements. Then an index matched epoxy was selected for incorporation of these nanoparticles to prepare transparent nanocomposite scintillators. In addition, colloidal solutions of CdTe QDs with various emitting colors were synthesized and incorporated into a Polymethyl-methacrylate (PMMA) matrix to make transparent nanocomposites. An initial evaluation of the scintillation behavior of these nanocomposites was evaluated by exposure to gamma rays.

Keywords

absorptionphotoemissionpolymer
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1312: Symposium HH/II/JJ – Polymer-Based Materials and Composites—Synthesis, Assembly and Applications , 2011 , mrsf10-1312-ii10-10
Copyright
Copyright © Materials Research Society 2011

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References

REFERENCES

[1] Milbrath, B. D., Peurrung, A. J., Bliss, M., Weber, W. J.: Radiation detector materials: An overview, Journal of Materials Research, 23, 2561, (2008)Google Scholar
[2] Letant, S. and Wang, T.: Semiconductor quantum dot scintillation under gamma-ray irradiation, Nano Lett., 6, 2877, (2006).Google Scholar
[3] McKigney, E. A., Del Sesto, R. E., Jacobsohn, L. G., et al. .: Nanocomposite scintillators for radiation detection and nuclear spectroscopy, Nuclear Instruments and Methods in Physcis Research, A (579) 15, (2007)Google Scholar
[4] Campbell, I. H. and Crone, B. K.: Quantum-dot/organic semiconductor composites for radiation detection, Adv. Mater., 18, 77, (2006)Google Scholar
[5] Burrell, A. K., Ott, K. C., Gordon, J. C., Del Sesto, R. E. and McCleskey, T. M., US patent 20080011956A1 Google Scholar
[6] Zhang, H., Wang, C., Li, M., Zhang, J., Lu, G., and Yang, B.: Fluorescent nanocrystal-polymer complexes with flexible processability. Adv. Mater. 17, 853, (2005)Google Scholar