Hostname: page-component-5c6d5d7d68-pkt8n Total loading time: 0 Render date: 2024-08-15T18:42:47.740Z Has data issue: false hasContentIssue false

Surface Characteristics of Monocrystalline ß-SiC dry etched in fluorinated gases

Published online by Cambridge University Press:  25 February 2011

John W. Palmour
Affiliation:
North Carolina State University, Department of Materials Science and Engineering, Box 7907. Raleigh, NC 27695–7907
R. F. Davis
Affiliation:
North Carolina State University, Department of Materials Science and Engineering, Box 7907. Raleigh, NC 27695–7907
P. Astell-Burt
Affiliation:
Plasma Technology, Inc., 145 Sidney Street, Cambridge, MA 02139
P. Blackborow
Affiliation:
Plasma Technology, Inc., 145 Sidney Street, Cambridge, MA 02139
Get access

Abstract

Monocrystalline ß-SiC (100) thin films were dry etched in CF4 and NF3 by reactive ion etching (RIE) and in SF6 by plasma etching. The etched surfaces were characterized by Auger Electron Spectroscopy (AES) and Scanning Electron Microscopy (SEM). The use of a stainless steel or an anodized Al cathode during RIE created a roughened SiC surface, which was contaminated with Fe or Al2 O3respectively. The roughness was caused by a micromasking effect produced by the deposition of these contaminants. By contrast, a carbon cathode yielded a very smooth and a much cleaner etched surface. Plasma etching of SiC in SF6 resulted in a very rough surface, but the AES spectra indicated almost no contamination and very little native oxide or fluorine. The optimal condition for etching SiC was determined to be RIE in NF 3 on a C cathode.

Type
Articles
Copyright
Copyright © Materials Research Society 1987

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Keyes, R. W., Silicon Carbide-1973, edited by Marshall, R. C., Faust, J. W. Jr., and Ryan, C. E., (University of South Carolina Press, Columbia, SC, 1974), p. 534.Google Scholar
2. Ryan, C. E., Silicon Carbide-1973, edited by Marshall, R. C., Faust, J. W. Jr., and Ryan, C. E., (University of South Carolina Press, Columbia, SC, 1974), p. 651.Google Scholar
3. Faust, J. W. Jr., Silicon Carbide -A High Temperature Semiconductor: 1959, edited by O'Connor, J. R. and Smiltens, J., New York, 1959), p. S331.Google Scholar
4. Winters, H. F., J. Vac. Sci. Technol. B 1, 927 (1980).Google Scholar
5. Sugiura, J., Lu, W. J., Cadien, K. C., and Steckl, A. J., J. Vac. Sci. Technol. B A, 349 (1986).Google Scholar
6. Lu, W. J., Steckl, A. J., Chow, T. P., and Katz, W., J. Electrochem. Soc., 131 1907 (1984).Google Scholar
7. Matsui, S. et al., Jpn. J. Appl. Phys. 20, L38 (1981).CrossRefGoogle Scholar
8. Palmour, J. W., Davis, R. F., Wallett, T. M., and Bhasin, K. B., J. Vac. Sci. Technol. A 4, 590 (1986).Google Scholar
9. Dohmae, S., Shibahara, K., Nishino, S., and Matsunami, H., Jap. J. of Appl. Phys.,24, L873 (1985).Google Scholar
10. Liaw, P. and Davis, R. F., J. Electrochem. Soc. 132 642 (1985).Google Scholar
11. Wang, D. N. K. (private communication).Google Scholar
12. Bower, D. H., J. Electrochem Soc. 129, 795 (1982).Google Scholar