Hostname: page-component-8448b6f56d-jr42d Total loading time: 0 Render date: 2024-04-19T10:29:51.618Z Has data issue: false hasContentIssue false

Study Of Nucleation And Growth Ev Al-Zn Alloys Using TEM

Published online by Cambridge University Press:  15 February 2011

G. Sundar
Affiliation:
Dept.of Mechanical and Materials Engg., Washington State Univ., Pullman, WA 99164
E. A. Kenik
Affiliation:
Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
J. J. Hoyt
Affiliation:
Dept.of Mechanical and Materials Engg., Washington State Univ., Pullman, WA 99164
S. Spooner
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831
Get access

Abstract

Nucleation and growth studies were conducted on Al-Zn alloys at several temperatures using transmission electron Microscopy (TEM) with an in-situ furnace. The value of the critical undercooling was established by noting the lowest temperature at which precipitates were no longer observed, following a quench into the two-phase metastable region. These results were compared with the Langer-Schwartz Model of nucleation and growth in which it is predicted that the half-completion time (i.e, the time required for the supersaturation to reach half its initial value) diverges for initial supersaturations which are higher than those predicted by the classical nucleation theory.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Gibbs, J.W., Collected works (Yale University Press, New Haven, CT, 1948),p.1.Google Scholar
2. Becker, R. and Doring, W., Ann. Phy. (N.Y) 24, 719 (1935).Google Scholar
3. Servi, I.S. and Tumbull, D., Acta Metall. 14, 161 (1966).Google Scholar
4. Kirkwood, D.H., Acta Metall. 18, 563 (1970).Google Scholar
5. Kirkwood, D.H. and West, A.W., Scripta Metall. 10, 687 (1976).Google Scholar
6. Hirata, T. and Kirkwood, D.H., Acta Metall. 25, 1425 (1977).Google Scholar
7. Sundquist, B.E. and Oriani, R.A., J. Chem. Phys. 36, 2604 (1962).Google Scholar
8. Heady, R.B. and Cahn, J.W., J. Chem. Phys. 58, 896 (1973).Google Scholar
9. Huang, J.S., Vernon, S. and Wong, N.-C., Phys. Rev. Lett. 33, 140 (1974).Google Scholar
10. Huang, J.S., Goldburg, W.I. and Muldover, M.R., Phys. Rev. Lett. 34, 639 (1975).Google Scholar
11. Binder, K. and Stauffer, D., Adv. Phys. 25, 343 (1976).Google Scholar
12. Langer, J.S. and Schwartz, A.J., Phy. Rev. A 21, 948 (1980).Google Scholar
13. Stanley, H.E. Introduction to Phase Transitions and Critical Phenomenon (New York: Oxford University Press, 1971).Google Scholar
14. Legoues, F.K. and Aaronson, H.I., Acta Metall. 32, 1855 (1984).Google Scholar
15. Simon, J.P., Guyot, P. and Ghilarducci de Salva, A., Philo. Mag. A 49, 151 (1984).Google Scholar
16. Sundar, G., Hoyt, J.J. and Spooner, S., Phys. Rev. B, 46, 14266 (1992).Google Scholar
17. Lasek, J., Czech. J. Phys. 15, 848 (1965).Google Scholar
18. Stephenson, G.B., Ludwig, K.F., Jordon-Sweet, J.L., Brauer, S., Mainville, J., Yang, Y.S., and Sutton, M., Rev. Sci. Instrum. 60, 1537 (1989).Google Scholar
19. Schwann, D., and Schmatz, W., Acta Metall. 26, 1571 (1978).Google Scholar
20. Rundman, K.B. and Hiliard, J.E., Acta Metall. 15, 1025 (1967).Google Scholar
21. Hoyt, J.J., Sluiter, M., Kraitchmann, M., and deFontaine, D., Acta Metall. 35, 2315 (1987).Google Scholar