Hostname: page-component-76fb5796d-25wd4 Total loading time: 0 Render date: 2024-04-26T22:38:11.584Z Has data issue: false hasContentIssue false

Statistical Study of the Effect of the Composition on the Strength of Supersulphated Cements

Published online by Cambridge University Press:  11 November 2013

Y.B. Castillo-Sánchez
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN (Cinvestav – Unidad Saltillo), México.
J.M. Almanza-Robles
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN (Cinvestav – Unidad Saltillo), México.
J.I. Escalante-García
Affiliation:
Centro de Investigación y de Estudios Avanzados del IPN (Cinvestav – Unidad Saltillo), México.
Get access

Abstract

Supersulphated cements (SSC) are environmentally friendly binders that incorporate several raw materials, including byproducts. A systematic study was considered opportune considering the wide range of formulations found in the literature. The effect of the type and proportioning of components in the strength of SC was investigated using the Taguchi method to optimize the experimental work and to define the optimal conditions. The factors were: [A] %blast furnace slag (82.5-90%), [B] CaSO4 - alkaline activator ratio (1:0, 3:1, 1:1, 1:3 and 0:1), [C] type of CaSO4 (5 types) and [D] type of alkaline activator (portland cement, Ca(OH)2, KOH and NaCO3 and 2 combinations of these). Pastes were prepared and characterized for up to 28 days at 20°C. In general, for all values of [A] the best strength was for levels of [C] at 3:1, followed by the 1:1 and 1:0 ratios. The optimal conditions using the 28 day strength consisted of [A]= 82.5%, [B]= 3:1, [C]= flyorgypsum and [D] = portland cement, which developed excellent strength from day one and 35MPa. X-ray diffraction showed ettringite and C-S-H formation from the early ages. The microstructures showed dense matrices of reaction products well bonded to partially reacted slag grains, which in some cases showed rims of hydration products.

Type
Articles
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Damtoft, J., et al. , “Sustainable Development and Climate Change Initiatives”, Cem Concr Res, 38 (2008) 115–127.Google Scholar
Dutta, D. and Borthakur, P., “Activation of Low Lime High Alumina Granulated Blast Furnace Slag by Anhydrite”, Cem Concr Res, 20 (1990) 711–722.Google Scholar
Valenti, G., “Hydration of Granulated Blast-Furnace Slag in the Presence of Phosphogypsum”, Elsevier Science Publishers 78 (1984) 101–112.Google Scholar
Grounds, T., et al. , “The Influence of Temperature and Different Storage Conditions on the Stability of Supersulphated Cement”, Journal of Thermal Analysis, (1995) 385–394.CrossRefGoogle Scholar
Erdem, E. and Olmez, H., “The Mechanical Properties of Supersulphated Cement Containing Phosphogypsum”, Cem Concr Res 23 115–121.CrossRefGoogle Scholar
Dongxu, L., et al. , “The Influence of Compound Admixtures on the Properties of High-Content Slag Cement”, Cem Concr Res 30 (2000) 45–50.CrossRefGoogle Scholar
Gruskovnjak, A., et al. , “Hydration Mechanisms of Super Sulphated Slag Cement” Cem Concr Res, 38 (2008) 983–992 Google Scholar
Tan, O., et al. “Taguchi Approach for Optimization of the Bleeding on Cement-Based Grouts” Tunnelling and Underground Space Technology 20 (2005) 167–173.CrossRefGoogle Scholar
Roy, R. “A Primer on the Taguchi Method”, B. Road, Canada (1994) 10–18.Google Scholar
Juenger, M., et al. , “Advances in Alternative Cementitious Binders”, Cem Concr Res 41 (2011) 1232–1243.CrossRefGoogle Scholar