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Stability and Icosahedral Transformation of Supercooled Liquid in Metal-Metal type Bulk Glassy Alloys

Published online by Cambridge University Press:  01 February 2011

Akihisa Inoue ,
Wei Zhnag ,
Dmitri V. Louzguine ,
Junji Saida  and
Eiichiro Matsubara
Akihisa Inoue
Affiliation:
Japan Science and Technology Agency, Sendai 980–8577, Japan
Wei Zhnag
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980–8577, Japan
Dmitri V. Louzguine
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980–8577, Japan
Junji Saida
Affiliation:
Center for Interdiciplinary Research, Tohoku University, Sendai 980–8578, Japan
Eiichiro Matsubara
Affiliation:
Institute for Materials Research, Tohoku University, Sendai 980–8577, Japan
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Abstract

The glassy structure and the primary precipitation phase from supercooled liquid were examined in metal-metal type Zr-, Hf- and Cu-based alloy systems by various advanced analytical techniques. The icosahedral phase precipitates as the primary phase from supercooled liquid for all the metal-metal type glassy alloys examined in the present study. The icosahedral phase has a rhombic triacontahedra type for the Zr-Al-Ni-Cu-NM (NM=Ag, Pd, Au, Pt), Zr-Cu-NM, Hf-Al-Ni-Cu-NM, Cu-Zr-Ti-Pd and Cu-Hf-Ti alloys. In addition, the short-range atomic configurations in their glassy alloys have the features of highly dense packed atomic configuration, new local atomic configurations and long-range homogeneity with attractive interaction. It is therefore concluded that the high glass-forming ability of the metal-metal type alloys is due to the self-formation of the unique glassy structure with the above-described three features which are consistent with the formation of short-range icosahedral atomic configuration.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 805: Symposium LL – Quasicrystals , 2003 , LL6.1/MM4.1
Copyright
Copyright © Materials Research Society 2004

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