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Spectroscopic Investigations of the Network Structure in Borovanadate Glasses

Published online by Cambridge University Press:  10 February 2011

O. Attos ,
M. Massot ,
H. S. Mavi  and
C. Julien
O. Attos
Affiliation:
Laboratoire de Physique des Solides, Université Pierre et Marie Curie, associé au CNRS (ERS 113), 4 place Jussieu, 75252 Paris cedex 05, France
M. Massot
Affiliation:
Laboratoire de Physique des Solides, Université Pierre et Marie Curie, associé au CNRS (ERS 113), 4 place Jussieu, 75252 Paris cedex 05, France
H. S. Mavi
Affiliation:
Laboratoire de Physique des Solides, Université Pierre et Marie Curie, associé au CNRS (ERS 113), 4 place Jussieu, 75252 Paris cedex 05, France
C. Julien
Affiliation:
Laboratoire de Physique des Solides, Université Pierre et Marie Curie, associé au CNRS (ERS 113), 4 place Jussieu, 75252 Paris cedex 05, France
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Abstract

Borovanadate glasses with mixed conductivity, i.e., simultaneous ionic and electronic carriers have been obtained in the system (100−x)[B2O3-Li2O]-xV2O5 (0 ≤ x ≤ 30 mole%). To understand the origin of the conductivity in these glasses, the compositional dependence of the network structure has been studied by Raman and infrared spectroscopy.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 455: Symposium T – Glasses and Glass Formers–Current Issues , 1996 , 477
Copyright
Copyright © Materials Research Society 1997

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References

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