Hostname: page-component-76fb5796d-25wd4 Total loading time: 0 Render date: 2024-04-27T03:23:10.510Z Has data issue: false hasContentIssue false
  • English
  • Français

Solvate Ionic Liquids and Their Application to Lithium Batteries: Glyme-Lithium Bis(fluorosulfonyl)amide Equimolar Complexes

Published online by Cambridge University Press:  25 October 2012

Kazuki Yoshida ,
Mizuho Tsuchiya ,
Naoki Tachikawa ,
Kaoru Dokko  and
Masayoshi Watanabe
Kazuki Yoshida
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Mizuho Tsuchiya
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Naoki Tachikawa
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Kaoru Dokko
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Masayoshi Watanabe
Affiliation:
Department of Chemistry and Biotechnology, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
Get access

Abstract

The physicochemical properties of glyme-Li[FSA] (FSA: bis(fluorosulfonyl)amide) equimolar complexes were investigated. The self-diffusion coefficients of glymes and Li+ as determined by pulsed-field gradient spin-echo nuclear magnetic resonance spectroscopy in equimolar complexes were almost identical, suggesting that all of the glyme molecules coordinated with Li+. Electrochemical characterization revealed that the oxidative stability of glyme molecules was enhanced by complexing with Li+. Using [Li(glyme)1][FSA] electrolytes and a LiFePO4cathode, a lithium secondary battery could be stably operated for more than 100 cycles at room temperature.

Keywords

energy storageenergetic materialionic conductor
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1473: Symposium BBB – Functional Materials and Ionic Liquids , 2012 , mrss12-1473-bbb02-03
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Armand, M. and Tarascon, J.-M., Nature, 451, 652 (2008).10.1038/451652aCrossRefGoogle Scholar
Garcia, B., Lavallée, S., Perron, G., Michot, C., and Armand, M., Electrochim. Acta, 49, 4583 (2004).10.1016/j.electacta.2004.04.041CrossRefGoogle Scholar
Tachikawa, N., Park, J.-W., Yoshida, K., Tamura, T., Dokko, K., and Watanabe, M., Electrochemistry, 5, 349 (2010).10.5796/electrochemistry.78.349CrossRefGoogle Scholar
Shobukawa, H., Tokuda, H., Tabata, S., and Watanabe, M., Electrochim. Acta, 50, 304 (2004).10.1016/j.electacta.2004.01.096CrossRefGoogle Scholar
Shobukawa, H., Tokuda, H., Susan, M.A.B.H., and Watanabe, M., Electrochim. Acta, 50, 3872 (2005).10.1016/j.electacta.2005.02.043CrossRefGoogle Scholar
Yoshida, K., Nakamura, M., Kazue, Y., Tachikawa, N., Tsuzuki, S., Seki, S., Dokko, K., and Watanabe, M, J. Am. Chem. Soc., 133, 13121 (2011).10.1021/ja203983rCrossRefGoogle Scholar
Tamura, T., Hachida, T., Yoshida, K., Tachikawa, N., Dokko, K., and Watanabe, M., J. Power Sources, 195, 6095 (2010).10.1016/j.jpowsour.2009.11.061CrossRefGoogle Scholar
Tamura, T., Yoshida, K., Hachida, T., Tsuchiya, M., Nakamura, M., Kazue, Y., Tachikawa, N., Dokko, K., and Watanabe, M., Chem. Lett., 39, 753 (2010).10.1246/cl.2010.753CrossRefGoogle Scholar
Yoshida, K., Tsuchiya, M., Tachikawa, N., Dokko, K., and Watanabe, M., J. Phys. Chem. C, 115, 18384 (2011).10.1021/jp206881tCrossRefGoogle Scholar
Angell, C.A., Ansari, Y., Zhao, Z.F., Faraday Discuss., 154, 9 (2011).10.1039/C1FD00112DCrossRefGoogle Scholar
Matsumoto, H., Sakaebe, H., Tatsumi, K., Kikuta, M., Ishiko, E., and Kono, M., J. Power Sources, 160, 1308 (2006).10.1016/j.jpowsour.2006.02.018CrossRefGoogle Scholar
Ishikawa, M., Sugimoto, T., Kikuta, M., Ishiko, E., and Kono, M., Journal of Power Sources, 162, 658 (2006).10.1016/j.jpowsour.2006.02.077CrossRefGoogle Scholar
Tokuda, H., Tsuzuki, S., Susan, M.A.B.H., Hayamizu, K., and Watanabe, M., J. Phys. Chem. B, 110, 19593 (2006).10.1021/jp064159vCrossRefGoogle Scholar