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Silicon Oxycarbide Glasses from Sol-Gel Precursors

Published online by Cambridge University Press:  25 February 2011

F. Babonneau ,
G. D. Soraru ,
G. D'Andrea ,
S. Dire  and
L. Bois
F. Babonneau
Affiliation:
Chimie de la Matière Condensée, Université P. et M. Curie, 4 place Jussieu, 75252 Paris, France.
G. D. Soraru
Affiliation:
Dipartimento di Ingegneria dei Materiali, Università di Trento, 38050, Mesiano-Trento, Italy.
G. D'Andrea
Affiliation:
Dipartimento di Ingegneria dei Materiali, Università di Trento, 38050, Mesiano-Trento, Italy.
S. Dire
Affiliation:
Dipartimento di Ingegneria dei Materiali, Università di Trento, 38050, Mesiano-Trento, Italy.
L. Bois
Affiliation:
Chimie de la Matière Condensée, Université P. et M. Curie, 4 place Jussieu, 75252 Paris, France.
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Abstract

Silicon oxycarbide glasses have been prepared from sol-gel precursors containing not only Si-CH3, but also Si-H bonds. Three systems have been chosen containing various Si units but the same C/Si ratio. Their pyrolysis process has been mainly followed by 29Si MAS-NMR and the composition of the final glass extracted. This study shows that a suitable choice of Si-CH3 and Si-H functionnalized silicon alkoxides can lead to a strong decrease in the free carbon content and to an almost pure silicon oxycarbide phase.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 271: Symposium N – Better Ceramics Through Chemistry V , 1992 , 789
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Loehman, R. E., J. Non Cryst. Solids 56, 123 (1983).Google Scholar
2. Homeny, J., Nelson, G. G., Risbud, S. H., J. Am. Ceram. Soc. 71, 386 (1988).CrossRefGoogle Scholar
3. Babonneau, F., Thome, K., Mackenzie, J. D., Chem. Mater. 1, 554 (1989).CrossRefGoogle Scholar
4. Zhang, H., Pantano, C., J. Am. Ceram. Soc. 73, 958 (1990).CrossRefGoogle Scholar
5. Renlund, G. M., Pochazka, S., Doremus, R. H., J. Mater. Res. 6, 2716 (1991).Google Scholar
6. Babonneau, F., Bois, L., Livage, J., J. Non Cryst. Solids (in press).Google Scholar
7. Glaser, R. H., Wilkes, G. L., Bronnimann, C. E., J. Non Cryst. Solids 113, 73 (1985).Google Scholar
8. Belot, V., Corriu, R., Leclerca, D., Mutin, P. H., Vioux, A., Chem. Mater. 3, 127 (1991).Google Scholar