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Room Temperature Ferromagnetism in Spin-coated Anatase- and Rutile- Ti1-x Mx O2 ( M= Fe, Mn, Co) Films

Published online by Cambridge University Press:  31 January 2011

Danilo Barrionuevo
Affiliation:
danilo_23h@hotmail.comdanilo.barrionuevo@upr.edu
Surinder P Singh
Affiliation:
surinder.singh@upr.edu, Mayaguez, Puerto Rico
Maharaj S. Tomar
Affiliation:
maharajs.tomar@upr.edu, University of Puerto Rico, Department of Physics, Mayaguez, Puerto Rico
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Abstract

Diluted magnetic semiconductors (DMS) have been explored extensively, because of their potential application in spintronic devices. We studied the structural optical and magnetic properties of Ti1-xMxO2 (M= Fe, Mn, Co; x = 0.00, 0.05, 0.08, 0.10, 0.15, 0.20, 0.25, 0.30), thin films by sol-gel process and deposited using spin coating on Pt (Pt/Ti/SiO2/Si) and quartz substrates. X-ray diffraction studies and Raman spectroscopy reveal anatase and rutile phases of the synthesized films when annealed at 500 and 10000 C, respectively. Optical transmission measurements show high degree of transparency that decreases with increase in transition metal ion concentration. The films show room temperature ferromagnetism, suggesting their potential in spin based heterojunction devices.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

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References

1 Gary, A. P., Science 282, 1660 (1998)Google Scholar
2 Wolf, S. A., Awschalom, D. D., Buhrman, R. A., Daughton, J. M., Molnar, S. V., Roukes, M. L., Chtchelkanova, A. Y. and Treger, D. M., Science 294, 1488–95 (1998)10.1126/science.1065389Google Scholar
3 Ohno, H., Science 281, 951 (1998)10.1126/science.281.5379.951Google Scholar
4 Park, M.S., Min, B.I., Phys. Rev. B 68, 033202 (2003)10.1103/PhysRevB.68.033202Google Scholar
5 Pearton, S. J.; Heo, W. H.; Ivill, M.; Norton, D. P.; Steiner, T. Semicond. Sci. Technol, 19, R59 (2004)10.1088/0268-1242/19/10/R01Google Scholar
6 Wolf, S. A., Awschalom, D. D., Buhrman, R. A., Daughton, J. M., Molnar, S. V., Roukes, M. L., Chetchalkanova, A. Y and Treger, D. M., Science 294, 1488 (2001)10.1126/science.1065389Google Scholar
7 Suryanarayanan, R., J. Phys.: Condens. Matter 17, 755762 (2005)Google Scholar
8 Huang, Chunming, Thin Solid Films 505, 141 (2006)10.1016/j.tsf.2005.10.021Google Scholar
9 Weng, W., Ma, M., Du, P., Zhao, G., Shen, G., Wang, J., Han, G., Surface & Coatings Technology 198, 340 (2005)10.1016/j.surfcoat.2004.10.071Google Scholar
10 Deng, Q., Gao, Y., Xia, X., Chen, R., Wan, L., Shao, G., Journal of Physics: Conference Series 152, 012073 (2009)Google Scholar
11 Xu, C., Killmeyer, R., McMahan, L., Shahed, U., Electrochemistry Communications 8, 1650 (2006)10.1016/j.elecom.2006.07.018Google Scholar
12 Aita, C.R., Appl. Phys. Lett. 90, 213112 (2007)10.1063/1.2742914Google Scholar
13 Orendorz, A., Brodyanski, A., Losch, J., Bai, L.H., Chen, Z.H., Le, Y.K., Ziegler, C., Gnaser, H., Surf. Sci. 601, 4390 (2007)10.1016/j.susc.2007.04.127Google Scholar
14 Mazza, T., Barborini, E., Piseri, P., Milani, P., Cattaneo, D., Bassi, A.L., Bottani, C.E., Ducati, C., Phy. Rev. B 75, 045416 (2007)10.1103/PhysRevB.75.045416Google Scholar
15 Djaoued, Y., Badilescu, S., Ashrit, P.V., Bersani, D., Lottici, P.P., Robichaud, J., Proc. SPIE 4469, 70 (2001)10.1117/12.447375Google Scholar
16 Orendorz, A., Brodyanski, A., Losch, J., Bai, L.H., Chen, Z.H., Le, Y.K., Ziegler, C., Gnaser, H., Surf. Sci. 601, 4390 (2007)10.1016/j.susc.2007.04.127Google Scholar