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Reactive Ion Etch of GaAs and AIGaAs Using BCl3, SiCl4 and SF6.Instead of CCl2F2

Published online by Cambridge University Press:  15 February 2011

J. W. Wu
Affiliation:
Institute of Electronics National Chiao Tung University, Hsinchu, Taiwan, ROC.
C. Y. Chang
Affiliation:
Institute of Electronics National Chiao Tung University, Hsinchu, Taiwan, ROC.
K. C. Lin
Affiliation:
Institute of Electronics National Chiao Tung University, Hsinchu, Taiwan, ROC.
E. Y. Chang
Affiliation:
Institute of Materials Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan, ROC.
J. H. Hwang
Affiliation:
Institute of Materials Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan, ROC.
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Abstract

In the past, CCl2F2 had been widely used in the dry etching process of the GaAs-based materials, However, it causes ozone depletion and is detrimental to the environment. In order to prevent further ozone depletion, it is necessary to search for some substitutedl gases. In this study, chloric gases, like BCl3 and SiCl4, were used to provide an alternative way for the reactive ion etch of GaAs and AlGaAs. To provide high etching selectivity between GaAs and AlGaAs, a fluorine containing gas SF6 is added, to increase the etch rate of GaAs than that of AlGaAs, which is due to the formation of non-volatile solid AlF3. In this study the etching characteristics of the BCl3/SF6, SiCl4/SF6 were studied and high etching selectivity between AlGaAs/GaAs is achieved.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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