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Pressure Evolution of a Bituminized Washing Water Concentrate During Leaching

Published online by Cambridge University Press:  15 February 2011

Alexander H. Waellisch*
Affiliation:
Section Dismantling and Waste Management, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland
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Abstract

In this investigation the swelling pressure of confined samples of a real waste form, consisting of bitumen containing washing water concentrate, was measured. The theoretically reachable swelling pressure was estimated as high as ∼ 273 bar (27 MPa).

A first simple experimental set-up was a sample of bituminized radwaste embedded in a cylinder of sintered bronze with a piezo-resistive pressure transducer. This was put into a leaching medium. A maximum pressure of 2 bar (0.2 MPa) was measured. The leaching rates of these confined samples were similar to those of unconfined ones.

The second set-up was a sample of bituminized radwaste embedded in a cylinder of stainless steel, also equipped with a pressure transducer. The open bottom of the cylinder was closed with a disc of porous cement with water/cement ratio of 1.3. In two similar experiments with this set-up the swelling pressure reached in one case a value of 9 bar = 0.9 MPa and in the second improved one about 15 bar = 1.5 MPa.

Type
Research Article
Copyright
Copyright © Materials Research Society 2009

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References

1 Marien, A., Smets, S, Li, X. and Valcke, E. in Scientific Basis for Nuclear Waste Management XXXI, MRS Symp. Proc., Vol. 1107, 2008, pp.151159.Google Scholar
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