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Polysilicon thin Films and Devices Produced by Low-Temperature (600°C) Furnace Crystallisation of Hydrogenated Amorphous Silicon (a-Si:H)

Published online by Cambridge University Press:  28 February 2011

T. E. Dyer ,
J. M. Marshall ,
W. Pickin ,
A. R. Hepburn  and
J. F. Davffis
T. E. Dyer
Affiliation:
Department of Materials Engineering, University College of Swansea, Singleton Park, Swansea SA2 8PP, U.K.
J. M. Marshall
Affiliation:
Department of Materials Engineering, University College of Swansea, Singleton Park, Swansea SA2 8PP, U.K.
W. Pickin
Affiliation:
Department of Materials Engineering, University College of Swansea, Singleton Park, Swansea SA2 8PP, U.K.
A. R. Hepburn
Affiliation:
Department of Materials Engineering, University College of Swansea, Singleton Park, Swansea SA2 8PP, U.K.
J. F. Davffis
Affiliation:
Department of Materials Engineering, University College of Swansea, Singleton Park, Swansea SA2 8PP, U.K.
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Abstract

In this work, we report on the electronic properties of polysilicon thin films and devices realised via furnace crystallisation of undoped a-Si: H. The onset of crystallisation, degree of amorphisation and average grain size are determined by UV reflectivity and electron microscopy. Grain size is found to increase with decreasing a-Si:H substrate temperature, and a maximum areal grain size of 0.4μm2 is obtained. Optical absorption, DC conductivity and transient photoconductivity measurements are employed to examine carrier transport mechanisms. We observe a Meyer-Neldel relationship between the DC conductivity prefactor σ0 and activation energy Eσ. A plasma hydrogenation treatment of the as-crystallised films results in an order of magnitude increase in the DC conductivity and a similar increase in photoconductivity. This is consistent with a shift of the Fermi level position 0.06 eV towards the conduction band. Additionally, analysis of the transient photoconductivity infers a reduced density of states. We discuss the implications of our results for polysilicon TFT optimisation.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 283: Symposium F – Microcrystalline Semiconductors–Materials Science and Devices , 1992 , 691
Copyright
Copyright © Materials Research Society 1993

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