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Ordered Defect-Fluorite Compounds in ZrO2 Alloys

Published online by Cambridge University Press:  21 February 2011

S. Farmer
Affiliation:
Case Western Reserve University, Department of Metallurgy and Materials Science, Cleveland Ohio 44106
J. Hangas
Affiliation:
Case Western Reserve University, Department of Metallurgy and Materials Science, Cleveland Ohio 44106
V. Lanteri
Affiliation:
Case Western Reserve University, Department of Metallurgy and Materials Science, Cleveland Ohio 44106
T.E. Mitchell
Affiliation:
Case Western Reserve University, Department of Metallurgy and Materials Science, Cleveland Ohio 44106
A.H. Heuer
Affiliation:
Case Western Reserve University, Department of Metallurgy and Materials Science, Cleveland Ohio 44106
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Abstract

Intermediate ordered-defect fluorite compounds are an important component of ZrO2 alloys containing the aliovalent solutes MgO, CaO, or Y2O3. These compounds also form in oxygen-deficient rare earth oxides and in other ternary oxides based on the fluorite structure, and can best be studied by TEM. Examples are given of such phases in the MgO-ZrO2, Y2O3-ZrO2, and CaO-ZrO2 systems.

Type
Research Article
Copyright
Copyright © Materials Research Society 2006

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References

REFERENCES

1. Heuer, A.H. and Rühle, M., Adv. in Ceramics, Science and Technology of Zirconia, eds. Claussen, N. Rühle, M. and Heuer, A.H., The Amer. Cer. Soc., (1984). To be published.Google Scholar
2. Ruff, O. and Ebert, F.; Z. anorg. allg. Chem., 180, 19 (1929).Google Scholar
3. Heuer, A.H., “Advances in Ceramics 3, Science and Technology of Zirconia”, ed. Heuer, A.H. and Hobbs, L.W., Amer. Cer. Soc., 98115 (1981).Google Scholar
4. Claussen, N., Wagner, R., Gouckler, L.J. and Petzow, G., J. Amer. Cer. Soc., 61, 369370 (1968).CrossRefGoogle Scholar
5. Carter, R.E. and Roth, W.L.; in “Electromotive Force Measurements in High Temperature Systems. Institution of Mining and Metallurgy, 125144 (1968).Google Scholar
6. Morinaga, M., Cohen, J.B. and Faber, J. Jr., Acta Cryst., A–36, 520530 (1980).Google Scholar
7. Hagamark, K. and Broli, M., J. Inorg. Nucl. Chem., 28, 3632 (1966).Google Scholar
8. Eyring, L., in “Nonstoichiometric Oxides”, ed. Sorensen, O.T., Acad. Press Inc., 337398 (1981).Google Scholar
9. Bartram, S.F., Inorg. Chem., 5, 749754 (1966).Google Scholar
10. Thornber, M.R., Bevan, D.J.M. and Graham, J., Acta. Cryst., B24, 1181191 (1968).Google Scholar
11. Tvenge, R.T. and Eyring, L., J. of Solid State Chem., 29, 165179 (1979).Google Scholar
12. Grain, C.F., J. Amer. Cer. Soc., 50 (6), 288290 (1967).Google Scholar
13. Delamarre, C., “Hafnium Dioxide - MO Systems. Comparison with Corresponding Systems Based on Zirconia”, Rev. Int. Hautes Temper. et. Refract. 9 (2), 209224 (1972).Google Scholar
14. Yoranovitch, O. and Delamarre, C., Mat. Res. Bull., 11 (8), 10051010 (1976).Google Scholar
15. Hannink, R.H.J. and Garvie, R.C., J. Mat. Sci. 17, 26372643 (1982).Google Scholar
16. Hannink, R.H.J., J. Mat. Sci. 18, 457470 (1983).Google Scholar
17. Farmer, S.C., Schoenlein, L.H. and Heuer, A.H., J. Amer. Ceram. Soc. 66, 107109 (1983).Google Scholar
18. Bevan, D.J.M. and Summerville, E., “Handbook of the Physics and Chemistry of Rare Earths”, Vol. 3, ed. Gschneider, C.A. and Eyring, L., North-Holland Publishing Co, 401523 (1979).Google Scholar
19. Scott, H.G., J. Mat. Sci. 10 (1975) 1527.Google Scholar
20. Stubican, V.S. and Ray, S.P., J. Amer. Ceram. Soc. 60 (1977) 534.Google Scholar
21. Pascual, C. and Duran, P., J. Amer. Ceram. Soc. 66 (1983) 23.Google Scholar
22. Lanteri, V., Mitchell, T.E. and Heuer, A.H., in Ref. 1.Google Scholar
23. Rühle, M., Claussen, N. and Heuer, A.H., in Ref. 1.Google Scholar
24. Lanteri, V., Mitchell, T.E., Heuer, A.H. and Rühle, M., to be published.Google Scholar
25. Chaim, R., Rühle, M. and Heuer, A.H., to be published.Google Scholar
26. Allpress, J.G., Rossell, H.J. and Scott, H.G., J. Solid State Chem., 14, 264273 (1975).Google Scholar
27. Rossell, H.J. and Scott, H.G., J. Solid State Chem., 13, 345350 (1975).Google Scholar
28. Hellmann, J.R. and Stubucan, V.S., J. Amer. Cer. Soc., 66, 260264 (1983).Google Scholar
29. Marder, J.M., Mitchell, T.E. and Heuer, A.H., Acta Metall. 31, 387 (1983).Google Scholar
30. Hangas, J., Mitchell, T.E. and Heuer, A.H., in Ref. 1.Google Scholar
31. Stubican, V.S., Corman, G.S., Hellmann, J.R. and Senft, G., in Ref. 1.Google Scholar