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Optical Limiting With Neutral Nickel Dithiolene Complexes

  • W. L. Tan (a1), W. Ji (a1), J. L. Zuo (a2), J. F. Bai (a2), X. Z. You (a2), J. H. Lim (a3), S. S. Yang (a3), D. J. Hagan (a3) and E. W. Van Stryland (a3)...


We report an investigation of optical-limiting behavior in two neutral nickel complexes with multi-sulfur 1,2 dithiolene ligands, [Ni(medt)2] I (medt = 5,6-dihydro-6-methyl-1,4-dithiin-2,3- dithiolate) and [Ni(phdt)2] 2 (phdt = 5,6-dihydro-5-phenyl-l,4-dithiin-2,3-dithiolate) in benzene solution. The fluence-dependent transmission of the complexes was observed with nanosecond and picosecond laser pulses at 532-nm wavelength. The limiting thresholds of the complexes were ˜0.3 J/cm2, when measured with the picosecond pulses. Both picosecond time-resolved pump-probe and Z-scan measurement revealed that the limiting effects should originate from excited-state absorption and refraction. The transparency window (400˜900 nm), observed in the linear absorption spectra of the complexes, indicated that their limiting response should cover a wider range than those of fullerenes and phthalocyanines.



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