Hostname: page-component-8448b6f56d-m8qmq Total loading time: 0 Render date: 2024-04-18T21:17:34.745Z Has data issue: false hasContentIssue false
  • English
  • Français

Open Framework and Microporous Transition Metal Silicates

Published online by Cambridge University Press:  11 February 2011

Allan J. Jacobson ,
Xiqu Wang ,
Lumei Liu  and
Jin Huang
Allan J. Jacobson
Affiliation:
Department of Chemistry, University of Houston Houston, TX 77204, U.S.A.
Xiqu Wang
Affiliation:
Department of Chemistry, University of Houston Houston, TX 77204, U.S.A.
Lumei Liu
Affiliation:
Department of Chemistry, University of Houston Houston, TX 77204, U.S.A.
Jin Huang
Affiliation:
Department of Chemistry, University of Houston Houston, TX 77204, U.S.A.
Get access

Abstract

A family of microporous and open-framework microporous transition metal silicates have been prepared by hydrothermal synthesis at T ≤ 240 °C. The structures of the compound are based on a common principle in which anionic silicate components (layers, chains, or cluster anions) are connected by isolated transition metal polyhedra by sharing four corners in a square arrangement. Known examples of this class of compounds are reviewed and some recent progress on extending the syntheses to include organic templates are discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 755: Symposium DD – Solid-State Chemistry of Inorganic Materials IV , 2002 , DD3.6
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

For a recent review see Cheetham, A. K., Férey, G., Loiseau, T., Angew. Chem. Int. Ed., Engl. 38, 3268, (1999).Google Scholar
2. Rocha, J., Anderson, M. W., Eur. J. Inorg. Chem., 801, (2000).Google Scholar
3. Rocha, J., Brandão, P., Lin, Z., Anderson, M. W., Alfredsson, V., Terasaki, O., Angew. Chem. Int. Engl., 36, 100, (1997).Google Scholar
4. Wang, X., Liu, L., Jacobson, A. J., Angew. Chem. Int. Ed., 40, 2174, (2001).Google Scholar
5. Wang, X., Liu, L., Jacobson, A. J., J. Amer. Chem. Soc., 124, 7812, (2002).Google Scholar
6. Huang, J., Wang, X., Liu, L., Jacobson, A. J., Solid State Sciences, 4, 1193, (2002).Google Scholar
7. Wang, X., Huang, J., Liu, L., Jacobson, A. J., J. Mater. Chem., 12, 406, (2002).Google Scholar
8. Huang, J., Wang, X., Jacobson, A. J., J. Mater. Chem., (2002) in press.Google Scholar
9. Wang, X., Huang, J., Liu, L., Jacobson, A. J., unpublished results.Google Scholar
10. Li, H., Eddaoudi, M., Plevert, J., O'Keefe, M., Yaghi, O. M., J. Am. Chem. Soc., 122, 12409 (2000).Google Scholar
11. Francis, R. J., Jacobson, A. J., Chem. Mater. 13, 4676, (2001)Google Scholar
12. Wang, X., Huang, J., and Jacobson, Allan J., J. Amer. Chem. Soc. (2002) in press.Google Scholar