Hostname: page-component-848d4c4894-8kt4b Total loading time: 0 Render date: 2024-06-22T19:15:36.075Z Has data issue: false hasContentIssue false
  • English
  • Français

On The Study Of Grain Boundary Segregation Using X-Ray Diffraction And Computer Simulation

Published online by Cambridge University Press:  25 February 2011

C. A. Counterman ,
I. Majid ,
P. D. Bristowe  and
R. W. Balluffi
C. A. Counterman
Affiliation:
Department of Materials Science and Engineering Massachusetts Institute of Technology, Cambridge, MA 02139
I. Majid
Affiliation:
Department of Materials Science and Engineering Massachusetts Institute of Technology, Cambridge, MA 02139
P. D. Bristowe
Affiliation:
Department of Materials Science and Engineering Massachusetts Institute of Technology, Cambridge, MA 02139
R. W. Balluffi
Affiliation:
Department of Materials Science and Engineering Massachusetts Institute of Technology, Cambridge, MA 02139
Get access

Abstract

The possibility of studying grain boundary segregation using X-ray diffraction is explored by performing a computer simulation of the diffraction effects expected from the segregation of solute atoms to grain boundaries in two gold alloy systems, i.e. Au-Ag and Au-Ni. Using atomistic Monte-Carlo and molecular statics methods, equilibrium boundary structures are determined and analyzed by computing the grain boundary structure factors. Various changes in both relative and absolute grain boundary structure factors are found which can be directly related to structural and compositional changes due to segregation. In addition, systematic diffraction effects are found as a function of boundary misorientation. The experimental conditions required for verifying these predictions are discussed.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 238: Symposium Cb – Structure and Properties of Interfaces in Materials , 1991 , 499
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

[1] Taylor, M.S., Majid, I., Bristowe, P.D., and Balluffi, R.W.. Physical Review B, 40(5):2772–2778, 1989.CrossRefGoogle Scholar
[2] Majid, I., Bristowe, P.D., and Balluffi, R.W.. Physical Review B, 40(5):2779–2792, 1989.CrossRefGoogle Scholar
[3] Gaudig, W. and Sass, S.L.. Philosophical Magazine A, 39(6):725–741, 1979.CrossRefGoogle Scholar
[4] Budai, J., Bristowe, P.D., and Sass, S.L.. Acta Metallurgica, 31(5):6991–712, 1983.Google Scholar
[5] Fitzsimmons, M.R. and Sass, S.L.. Acta Metallurgica, 36(12):3103–3122, 1988.Google Scholar
[6] Fitzsimmons, M.R. and Sass, S.L.. Acta Metallurgica, 37(4):1009–1022, 1989.Google Scholar
[7] Bristowe, P.D. and Sass, S.L.. Acta Metallurgica, 28(5):575–588, 1980.Google Scholar
[8] Foiles, S.M.. Physical Review B, 32(12):7685–7693, 1985.Google Scholar
[9] Daw, M.S. and Baskes, M.I.. Physical Review Letters, 50(17):1285–1288, 1983.CrossRefGoogle Scholar
[10] Daw, M.S. and Baskes, M.I.. Physical Review B, 29(12):6443–6453, 1984.Google Scholar
[11] Daw, M.S.. in Vitek, V. and Srolovitz, D.J., editors, Atomistic Simulation of Materials: Beyond Pair Potentials, pages 181–191. Plenum Press, New York, 1989.Google Scholar
[12] Foiles, S.M., Baskes, M.I., and Daw, M.S.. Physical Review B, 33(12):7983–7991, 1986.CrossRefGoogle Scholar
[13] Foiles, S.M., Baskes, M.I., and Daw, M.S.. Physical Review B, 37(17):10378, 1988.Google Scholar
[14] Brokman, A. and Balluffi, R.W.. Acta Metallurgica, 31(10): 1639–1647, 1983.CrossRefGoogle Scholar
[15] Counterman, C.A.. PhD thesis, Massachusetts Institute of Technology, 1991.Google Scholar
[16] Foiles, S.M. and Seidman, D.N.. MRS Bulletin, XV(9):51–57, 1990.Google Scholar
[17] Budai, J., Donald, A.M., and Sass, S.L.. Scripta Metallurgica, 16(4):393–398, 1982.Google Scholar
[18] Budai, J. and Sass, S.L.. Journal de Physique, 43(C6):103–113, 1982.Google Scholar
[19] Foiles, S.M.. Acta Metallurgica, 37(10):2815–2821, 1989.CrossRefGoogle Scholar