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Al-Hussaini, Ayman S. 2017. In situ oxidative copolymerization and characterization of new poly(benzidine-co-o-phenylenediamine)/kaolinite microcomposites. Polymer Science, Series B, Vol. 59, Issue. 3, p. 372.
Laird, Eric D. and Li, Christopher Y. 2017. Nanomaterials Handbook. p. 103.
Moustafa, H. Duquesne, S. Haidar, B. and Vallat, M.F. 2017. Influence of the degree of exfoliation of an organoclay on the flame-retardant properties of cross-linked ethylene-co-Propylene-co-diene monomer-g-Maleic anhydride-based composites. Polymer Composites, Vol. 38, Issue. 5, p. 966.
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Al-Hussaini, Ayman S. and Eldars, Waleed 2016. Cheap Synthesis, Characterization and Antibacterial Efficacy of New Copoly(o-Nitroaniline-co-o-Phenylenediamine) Emeraldine Base/Bentonite Composites. Journal of Inorganic and Organometallic Polymers and Materials, Vol. 26, Issue. 3, p. 691.
Burgaz, Engin 2016. Polymer Nanocomposites. p. 191.
Khoshnazar, Rahil Beaudoin, James J. Raki, Laila and Alizadeh, Rouhollah 2016. Durability and mechanical properties of C–S–H/nitrobenzoic acid composite systems. Materials and Structures, Vol. 49, Issue. 12, p. 5315.
Klonos, Panagiotis Kyritsis, Apostolos and Pissis, Polycarpos 2016. Interface/Interphase in Polymer Nanocomposites. p. 191.
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ζ-Caprolactam was polymerized in the interlayer spacing of montmorillonite, a clay mineral, yielding a nylon 6-clay hybrid (NCH) 1).
X-ray and TEM measurements revealed that each template of the silicate, which is 10 Å thick, was dispersed in the nylon 6 matrix and that the repeat unit increased from 12 Å in unintercalated material to 21 Å in the intercalated material.
Thus NCH, is a “polymer based molecular composite” or “nanometer composite”. NCH, when injection-molded, shows excellent properties as compared to nylon 6 in terms of tensile strength, tensile modulus and heat resistance. Heat distortion temperature increased from 65 °c for nylon 6 to 152 °c for NCH, containing 4 wt% (1.6 vol%) of clay mineral.
Hide All1. Presented in part at the 194th National Meetings of American Chemical Society, New Orleans, La., August 1987, Polymer Preprint 28, 447 (1987).2. Kohan, M. I. Ed., “Nylon Plastics”, Interscience, New York 1973.
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