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A New Type of Coordination Polymer: Hydrothermal Synthesis, Crystal Structure, and Magnetic Properties of [(C10H8N2)2CuBr]Cu3Br4

Published online by Cambridge University Press:  16 February 2011

Brenda R. Cabrera ,
Ru-Ji Wang ,
Jing Li  and
Tan Yuen
Brenda R. Cabrera
Affiliation:
Department of Chemistry, Rutgers University, Camden, NJ 08102, jingli@crab.rutgers.edu
Ru-Ji Wang
Affiliation:
Department of Chemistry, Rutgers University, Camden, NJ 08102, jingli@crab.rutgers.edu
Jing Li
Affiliation:
Department of Chemistry, Rutgers University, Camden, NJ 08102, jingli@crab.rutgers.edu
Tan Yuen
Affiliation:
Department of Physics, Temple University, Philadelphia, PA 19122
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Abstract

Growth of [(C10H8N2)2CuBr]Cu3Br4(I) crystals was achieved using the hydrothermal synthesis. Single crystal X-ray diffraction analysis shows that this compound crystallizes in monoclinic system, space group P21/c (no. 14) with four formula units in the unit cell. The cell dimensions are the following: a = 16.769(2) Å, b = 23.873(6) Å, c = 6.523(2) Å, β = 98.37(3)°, V = 2584(1) Å3. The title compound represents a new structure type. It consists of one-dimensional ribbons of 1[(Cu3Br4)] extending along the c-axis and discrete [(C10H8N2)2CuBr]+ complexes. The magnetic susceptibility study indicates a paramagnetic behavior due to the Cu(II) in the complex cations. The effective paramagnetic moment was calculated to be 2.20 μB from fitting the χ(T) data.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 547: Symposium DD – Solid-State Chemistry of Inorganic Materials II , 1998 , 493
Copyright
Copyright © Materials Research Society 1999

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References

1. Kawata, S., Kondo, M., Angew. Chem. Int. Ed. Engl. 1994, 116, 1151.Google Scholar
2. Kobel, W., Hanack, M., Inorg. Chem. 1986, 25, 103.Google Scholar
3. Fujita, M., Kwon, Y., Washizu, S., Ogura, K., J. Am. Chem. Soc. 1994, 116, 1151.Google Scholar
4. Carlucci, L., Ciani, G., Proserpio, D. M., Sironi, A., J. Am. Chem. Soc. 1995, 117, 4562.Google Scholar
5. MacGillivray, L., Subramanian, S., J. Chem. Soc. Commu. 1994, 1325.Google Scholar
6. Yaghi, O. M., Li, H., J. Am. Chem. Soc. 1995, 117, 10401.Google Scholar
7. Lu, J. Y., Cabrera, B. R., Wang, R., Li, J., Inorg. Chem. 1998, 37, 4480.Google Scholar
8. Lu, J. Y., Lawandy, M. A., Li, J., J. Am. Chem. Soc. submittedGoogle Scholar
9. Lu, J. Y., Cabrera, B. R., Li, J., Inorg. Chem. SubmittedGoogle Scholar
10. Kofmann, G., Hubber, R., Acta Crystallogr. 1968, A24, 348 Google Scholar
11. Sheldrick, G. M., SHELX-97: program for structure refinement: Univ. of Goettingen: Germany, 1997.Google Scholar
12. Keller, E., SCHAKAL 92: a computer program for the graphical representation of crystallographic models: University of Freiburg: Germany, 1992.Google Scholar