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A New Synthetic Route to Alkyl Terminated Silicon Nanoparticles.

Published online by Cambridge University Press:  11 February 2011

Katherine A. Pettigrew ,
Philip P. Power  and
Susan M. Kauzlarich
Katherine A. Pettigrew
Affiliation:
Department of Chemistry, One Shields Ave, University of California, Davis, CA 95616
Philip P. Power
Affiliation:
Department of Chemistry, One Shields Ave, University of California, Davis, CA 95616
Susan M. Kauzlarich
Affiliation:
Department of Chemistry, One Shields Ave, University of California, Davis, CA 95616
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Abstract

This paper describes the preparation of alkyl terminated silicon nanoparticles that are air and moisture stable by the oxidation of magnesium silicide with bromine and then the subsequent termination with an alkyl Grignard reagent. The nanoparticles have been characterized by transmission electron microscopy (TEM), high-resolution TEM (HRTEM), energy-dispersive X-ray spectroscopy (EDS), Fourier transform infrared (FTIR) spectroscopy, and fluorescence spectroscopy.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 737 , 2002 , F1.8
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

Heath, J. R., Science (USA) 1992, 258, 1131.Google Scholar
2. Wilcoxon, J. P.; Samara, G. A.; Provencio, P. N., Phys. Rev. B, Condens. Matter (USA) 1999, 60, 2704.Google Scholar
3. Wilcoxon, J. P.; Samara, G. A., Appl. Phys. Lett. (USA) 1999, 74, 3164.Google Scholar
4. Yang, C. S.; Bley, R. A.; Kauzlarich, S. M.; Lee, H. W. H.; Delgado, G. R., J Am Chem Soc 1999, 121, 5191.Google Scholar
5. Yang, C. S.; Kauzlarich, S. M.; Wang, Y. C.; Lee, H. W. H., J Clust Sci 2000, 11, 423.Google Scholar
6. Holmes, J. D.; Ziegler, K. J.; Doty, R. C.; Pell, L. E.; Johnston, K. P.; Korgel, B. A., J Am Chem Soc 2001, 123, 3743.Google Scholar
7. Harwell, D. E. In UH Reference No. 00227: USA, 2002.Google Scholar
8. Lee, H. W. H.; Thielen, P. A.; Delgado, G. R.; Kauzlarich, S. M.; Yang, C.-S.; Taylor, B. R., Critical Reviews in Optical Scence and Technology. 2000, CR77(Novel Materials and Crystal Growth Techniques for Nonlinear Optical Devices), 147.Google Scholar
9. Belomoin, G.; Therrien, J.; Smith, A.; Rao, S.; Twesten, R.; Chaieb, S.; Nayfeh, M. H.; Wagner, L.; Mitas, L., App. Phys. Lett. 2002, 80, 841.Google Scholar
10. English, D. S.; Pell, L. E.; Yu, Z.; Barbara, P. F.; Korgel, B. A., Nano Lett. 2002, 2, 681.Google Scholar
11. Bley, R. A.; Kauzlarich, S. M., J Am Chem Soc 1996, 118, 12461.Google Scholar
12. Bley, R. A.; Kauzlarich, S. M. In Nanoparticles and Nanostructures Films; Fendler, J. H., Ed.; Wiley-VCH: Weinheim, 1998; pp 101.Google Scholar
13. Mayeri, D.; Phillips, B. L.; Augustine, M. P.; Kauzlarich, S. M., Chem Mater 2001, 13, 765.Google Scholar
14. Baldwin, R. K.; Pettigrew, K. A.; Ratai, E.; Augustin, M. P.; Kauzlarich, S. M., Chem. Comm. 2002, 1822.Google Scholar
15. Baldwin, R. K.; Pettigrew, K. A.; Garno, J. C.; Power, P. P.; Liu, G. Y.; Kauzlarich, S. M., J Am Chem Soc 2002, 124, 1150.Google Scholar
16. Kauzlarich, S. M.; Chan, J. Y.; Taylor, B. R. In Inorganic Materials Synthesis; Winter, C. H., Hoffman, D. M., Eds.; American Chemical Society: Washington D.C., 1999; Vol. ACS Symposium Series Vol. 727, pp 15.Google Scholar
17. Li, G. H.; Gill, H. S.; Varin, R. A., Metall. Trans. A, Phys. Metall. Mater. Sci. (USA) 1993, 24A, 2383.Google Scholar
18. Puzder, A.; Williamson, A.J.; Grossman, J.C.; Galli, G., J. Chem. Phys. 2002, 117(14), 6721.Google Scholar