Hostname: page-component-8448b6f56d-tj2md Total loading time: 0 Render date: 2024-04-25T04:32:23.711Z Has data issue: false hasContentIssue false
  • English
  • Français

Multicomponent Materials as Li+ Conductors

Published online by Cambridge University Press:  01 February 2011

Susan Babinec ,
Huiqing Zhang ,
Andrew Talik  and
Valeriy Ginzburg
Susan Babinec
Affiliation:
Nicole Wagner Corporate Materials Research & Development, The Dow Chemical Company Midland, MI 48672
Huiqing Zhang
Affiliation:
Nicole Wagner Corporate Materials Research & Development, The Dow Chemical Company Midland, MI 48672
Andrew Talik
Affiliation:
Nicole Wagner Corporate Materials Research & Development, The Dow Chemical Company Midland, MI 48672
Valeriy Ginzburg
Affiliation:
Nicole Wagner Corporate Materials Research & Development, The Dow Chemical Company Midland, MI 48672
Get access

Abstract

The conductivity and mechanical stiffness of ethylene-oxide based Li+ conducting solid polymer electrolytes (SPE) were measured and compared for a variety of single- and two-phase systems. Our objective was to determine whether there are simple correlations between these two properties despite the fact that these systems are truly complex. Results show that molecular architecture dominates both transport and mechanical behavior of single phase systems, thereby eliminating broad correlations. Conductivity was additionally found to require not only facile local chain dynamics but also a sufficient concentration of vacancies, as per the site hopping model. Two phase systems also show complex behaviors, but offer a broader range of both conductivity and stiffness values, and good conductivity/stiffness correlations.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 856: Symposium BB – Multicomponent Polymer Systems-Phase Behavior, Dynamics, and Applications , 2004 , BB12.5
Copyright
Copyright © Materials Research Society 2005

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Wright, P., Br. Polym. J., 7, 319 (1975)Google Scholar
2. Armand, M., Chabagno, J., Duclot, M., Second International Meeting on Solid Electrolytes, St. Andrews Scotland, 20–22, Sept. 1978 Google Scholar
3. Soo, P., Huang, B., Jang, Y.-L., Chiang, Y.-M., Sadoway, D., Mayes, A., J. Electrochem. Soc., 146, 32 (1999)Google Scholar
4. Walls, H., Riley, M., Singhal, R., Spontak, R., Fedkiw, P., Khan, S., Adv. Funct. Mater., 13, 710 (2003)Google Scholar
5. Matsumiya, Y., Balsara, N., Kerr, J., Inoue, T., Watanabe, H., Macromol. 37, 544 (2004)Google Scholar
6. Ratner, M., Nitzan, A, Farad. Discuss. Chem. Soc., 88, 19 (1989)Google Scholar
7. Riley, M., Fedkiw, P., Khan, S., J. Electrochem. Soc., 149, A667 (2002)Google Scholar