Hostname: page-component-76fb5796d-25wd4 Total loading time: 0 Render date: 2024-04-26T18:06:13.163Z Has data issue: false hasContentIssue false
  • English
  • Français

Mps3 Layered Intercalates as Insulating Magnets: Towards Nanocomposites Associating Ferrimagnetism and Non-Linear Optical Properties

Published online by Cambridge University Press:  16 February 2011

Rene Clement  and
Pascal G. Lacroix
Rene Clement
Affiliation:
Laboratoire de Chimie Inorganique, CNRS URA 420, Université Paris Sud, Orsay, France.
Pascal G. Lacroix
Affiliation:
Laboratoire de Chimie Inorganique, CNRS URA 420, Université Paris Sud, Orsay, France.
Get access

Abstract

The layered MIIPS3 compounds posess a unique cation exchange intercalation chemistry, which allows the synthesis of a wide range of air stable M1-xPS3G2x intercalates (G stands here for a Monocation). The positive charge of the guest cations is counterbalanced by intralayer metallic vacancies.

Intercalation exerts a dramatic influence on the magnetic properties of these compounds. Whereas pristine MPS3 compounds order antiferromagnetically (M = Mn, Fe‥), Many intercalates become magnets below an ordering temperature that can be as high as 92 K. The role of intercalation is discussed in terms of the creation of intralayer metallic vacancies, which destroy the spin balance that prevails in pristine MPS3 compounds.

The MPS3 host lattice has the capability of causing spontaneous poling of the dimethylamino-N-Methyl stilbazolium chromophore (DAMS), leading to materials that exhibit strong second harmonic generation. (SHG). Inserting DAMS into MnPS3 therefore leads to a composite that possess both spontaneous Magnetization (below Tc = 40 K) and a strong efficiency for SHG.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 328: Symposium Q – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1993 , 319
Copyright
Copyright © Materials Research Society 1994

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Bree, R., Solid State Ionics, 22, 3, (1986).Google Scholar
2. Clément, R., J. Chem. Soc., Chem. Commun. 647, (1980); J. Am. Chem. Soc. 103, 6998 (1981).Google Scholar
3. Clément, R., Garnier, O. and Jegoudez, J., Inorg. Chem. 25 (9), 1404. (1986).Google Scholar
4. Lagadic, I., Léaustic, A., Clement, R., J. Chem. Soc., Chem. Commun. 1396 (1992).Google Scholar
5. Miller, J.S., Epstein, A.J., Reiff, W.M., Ace. Chem. Res. 21, 114 (1988).Google Scholar
6. Clement, R., Audiére, J.P., Renard, J.P., Rev. Chim. Minerale 19, 560 (1982).Google Scholar
7. CléMent, R. et al.in Inorganic and Organometallic Polymers with Specials Properties. edited by Laine, R.M. (Kluwer Academic Publishers, Dordrecht, 1992), p. 115.Google Scholar
8. Clément, R., Lagadic, I., Léaustic, A., Audière, J.P., Lomas, L., in Chemical Physics of Intercalation II, edited by Bernier, P. et al., (Plenum Press, New York, 1993), pp 315.Google Scholar
9. Clément, R., Lomas, L., Audiére, J.P., Chem. Mater. 2, 641 (1990).Google Scholar
10. Lacroix, P.G., Veret Lemarinier, A.V., Clément, R., Nakatani, K., Delaire, J., J. Mater. Chem. 3, 499 (1993).Google Scholar
11. Marder, S.R., Perry, J.W., Schaefer, W.P., Sciencer, 245, 626 (1989).Google Scholar
12. Lacroix, P. G., Clément, R., Nakatani, K., Zyss, J. and Ledoux, I., Science, in press.Google Scholar