Hostname: page-component-848d4c4894-wg55d Total loading time: 0 Render date: 2024-05-12T17:32:57.658Z Has data issue: false hasContentIssue false
  • English
  • Français

Modelling of the evolution of iron passivity: solving the moving boundaries problem

Published online by Cambridge University Press:  27 March 2012

Frantz A. Martin  and
Christian Bataillon
Frantz A. Martin
Affiliation:
CEA, DEN, DPC, SCCME, Laboratoire d’Etude de la Corrosion Aqueuse, F-91191 Gif-sur-Yvette
Christian Bataillon
Affiliation:
CEA, DEN, DPC, SCCME, Laboratoire d’Etude de la Corrosion Aqueuse, F-91191 Gif-sur-Yvette
Get access

Abstract

In the framework of long term prediction of corrosion in French geological repository systems, the modelling of the time evolution of the corrosion rate of iron over centuries is of high matter. The DPCM (Diffusion Poisson Coupled Model), implemented with the fully implicit CALIPSO numerical code can give access to the evolution of the oxide thickness grown on iron and the resulting corrosion rate. DPCM parameters for outer interfacial reactions have been set to fit to XANES experimental data provided by literature, and then the parameters for inner reaction rates have been evaluated from fitting to ellipsometry results taken from literature. The result is a good average fitting of the model to the experimental data.

Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1475: Symposium NW – Scientific Basis for Nuclear Waste Management XXXV , 2012 , imrc11-1475-nw35-o57
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Bataillon, C., Bouchon, F., Chainais-Hillairet, C., Desgranges, C., Hoarau, E., Martin, F., Perrin, S., Tupin, M., and Talandier, J., Electrochim. Acta 55, 4451 (2010).10.1016/j.electacta.2010.02.087Google Scholar
2. Chainais-Hillairet, C. and Bataillon, C., Numer. Math. 110, 1 (2008).10.1007/s00211-008-0154-xGoogle Scholar
3. Lu, Z. and Macdonald, D.D., Electrochim. Acta 53, 7696 (2008).10.1016/j.electacta.2008.05.021Google Scholar
4. Schmuki, P., Virtanen, S., Davenport, A.J., and Vitus, C.M., J. Electrochem. Soc. 143, 574 (1996).10.1149/1.1836483Google Scholar
5. Ohtsuka, T. and Yamada, H., Corros. Sci. 40, 1131 (1998).10.1016/S0010-938X(98)00015-8Google Scholar
6. Deng, H., Nanjo, H., Qian, P., Santosa, A., Ishikawa, I., and Kurata, Y., Electrochim. Acta 52, 4272 (2007).10.1016/j.electacta.2006.12.005Google Scholar