Hostname: page-component-848d4c4894-ndmmz Total loading time: 0 Render date: 2024-05-13T19:45:37.076Z Has data issue: false hasContentIssue false

Migration Behavior of Carbonate-14C in Tuffaceous Soil

Published online by Cambridge University Press:  15 February 2011

S. Nagao
Affiliation:
Department of Environmental Safety Research, Japan Atomic Energy Research Institute, Tokai-mura Naka-gun Ibaraki-ken 319–11, Japan
M. Senoo
Affiliation:
Department of Environmental Safety Research, Japan Atomic Energy Research Institute, Tokai-mura Naka-gun Ibaraki-ken 319–11, Japan
Get access

Abstract

A simple closed column system was developed to study migration of bicarbonate and carbonate 14C in soil layer. Experimental data for glass beads having less the 14C adsorption indicate that the system can be performed on column experiment keeping mass balance of 14C. Migration behavior of bicarbonate and carbonate 14C in a tuffaceous sandy soil was investigated by this column system in the pH range from 8 to 12. The 14C was delayed to tritiated water, and the retardation became stronger in order, pH 12 < pH 10 < pH 8. This is considered to be due to pH-dependent adsorption of bicarbonate and carbonate ions onto the soil sample.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Bush, R. P., Smith, G. M. and White, I. F., EUR 8749, Luxembourg 1984.Google Scholar
2. Hesbol, R., Puigdomenech, I. and Evans, S., SKB Technical Report 90–02, Stockholm 1990.Google Scholar
3. Allard, B., Torstenfelt, B. and Andersson, K., in Scientific Basis for Nuclear Waste Management III, edited by Moore, J. G. (Mater. Res. Soc. Symp. Proa, Plenum Press, New York 1980) pp. 465472.Google Scholar
4. Igarashi, T., Mahara, Y., Matsuda, N., Hirai, E. and Nakai, K., presented at 1992 Fall Meeting of the Atomic Energy Society of Japan, Nagoya, 1992 (unpublished).Google Scholar
5. Shoji, S. and Saigusa, M., Soil Sci. Plant Nutr., 23, 437455 (1977).Google Scholar
6. Boha, H. L., McNeal, B. L. and G. A. O’Connor, , Soil Chemistry, 2nd. ed. (John Wiley & Sons, New York, 1985), p. 341.Google Scholar
7. Nagao, S., Ogawa, H., Lee, Y.M. and Kamiyama, H., presented at 1993 Spring Meeting of the Atomic Energy Society of Japan, Kyoto, 1993 (unpublished).Google Scholar
8. Day, R. A. Jr. and Underwood, A. L., Quantitative Analysis, 4th ed. (Prentice-Hall, New Jersey, 1980).Google Scholar
9. Zachara, J. M., Girvin, D. C., Schmit, L. and Resch, C. T., Environ. Sci. Technol., 21, 589594 (1987).Google Scholar
10. Rundberg, R. S. and Albinsson, Y., LA-UR-91–3244, Los Alamos 1991.Google Scholar
11. Schulthess, C. P. and McCarthy, J. F., Soil Sci. Soc. Am. J., 54, 688694 (1990).Google Scholar
12. Hingstone, F. J, Atkinson, R. J., Posner, A. M. and Quirk, I. P., Nature, 215, 14591461 (1967).Google Scholar
13. Perrot, K. W., Smith, B. F. L. and Mitchell, B. D., J. Soil Sci., 27, 348356 (1976).Google Scholar
14. Wada, K., in Minerals in Soil Environments, edited by Dixon, J. B. and Weed, S. B. (Soil Sci. Soc. of Am., Wisconsin 1977) pp. 603–638.Google Scholar
15. Hingston, F. J., Posner, A. M. and Quirk, J. P., J. Soil Sci., 25, 1626 (1974).Google Scholar
16. Egawa, T., Sato, A. and Nishimura, T., Adv. Clay Sci., 2, 252262 (1960) (in Japanese).Google Scholar