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Mechanical Behavior of Molybdenum-Modified Cr3Si/Cr5Si3 Intermetallics

Published online by Cambridge University Press:  15 February 2011

M. Nazmy ,
C. Noseda ,
S. Augustin ,
P. Lipetzky  and
N. S. Stoloff
M. Nazmy
Affiliation:
Dept. of Materials Technology, ABB Power Generation Ltd., 5401 Baden, Switzerland
C. Noseda
Affiliation:
Dept. of Materials Technology, ABB Power Generation Ltd., 5401 Baden, Switzerland
S. Augustin
Affiliation:
Dept. of Materials Science and Engineering, Rensselear Poly. Inst., Troy, NY, USA
P. Lipetzky
Affiliation:
Dept. of Materials Science and Engineering, Rensselear Poly. Inst., Troy, NY, USA
N. S. Stoloff
Affiliation:
Dept. of Materials Science and Engineering, Rensselear Poly. Inst., Troy, NY, USA
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Abstract

Two molybdenum-modified chromium suicide base intermetallics have been prepared by powder metallurgy and investigated with respect to the hardness, flexural strength and fracture toughness at different temperatures. As toughening phase, tungsten, Pt-6%Rh and Saphikon fibres were tried to improve the toughness of these two intermetallics. The tungsten fibers generated microcracks in the base material due to the large mismatch in the coefficients of thermal expansion (CTE) between the fiber and the intermetallic. The Pt-6%Rh and Saphikon fibers did not exhibit such cracking.

An improvement in the fracture toughness was observed especially at elevated temperatures. The Saphikon fibers did not show interfacial reaction. Some limited diffusion of silicon was detected in the Pt-6%Rh phase after 1400°C treatment.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 460: Symposium Z – High-Temperature Ordered Intermetallic Alloys VII , 1996 , 727
Copyright
Copyright © Materials Research Society 1997

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References

REFERENCES

1. Petrovic, J.J. and Vasudevan, A.K., in Intermetallic Matrix Composites II, edited by Miracle, D.B., Anton, D.L. and Graves, J.A. (Mater. Res. Soc. Proc. 273, 1992) p. 229.Google Scholar
2. Kumar, K.S., Liu, C.T., J. of Metals 45 (6), p. 28 (1993).Google Scholar
3. Petrovic, J.J., MRS Bulletin 18 (7), p. 35 (1993).Google Scholar
4. Ghosh, A.K., Basu, A. and Kung, H. in Intermetallic Matrix Composites II, edited by Miracle, D.B., Anton, D.L. and Graves, J.A. (Mater. Res. Soc. Proc. 273, 1992) p. 259.Google Scholar
5. Shah, D. and Anton, D.L., Structural Intermetallics. edited by Darolia, R., Lewandowsky, J.J., Liu, C.T., Martin, P.L., Miracle, D. and Nathal, M. (TMS pub., Warrendale, PA, 1993) p. 755.Google Scholar
6. Fitzer, E. and , Renimele, in Fifth Int. Conf. on Composite Materials (ICCM-V, edited by Harrigan, W.C. Jr, Strife, J. and Dhingra, A.K. (AIME Pub., Warrendale, PA, 1985) p. 515.Google Scholar
7. Shah, D.M. and Anton, D.L., Mat. Sci. and Eng. A153, p. 402, (1992).Google Scholar
8. Newkirk, J.W. and Sago, J.A., in Intermetallic Matrix Composites, edited by Anton, D.L., Miracle, D.B. and McMeeking, R. (Mater. Res. Soc. Proc. 194, 1990) p. 183.Google Scholar
9. Bewlay, B.P., Chang, K.M., Sutlife, J.A. and Jackson, M.R., in Intermetallic Matrix Composites II, edited by Miracle, D.B., Anton, D.L. and Graves, J.A. (Mater. Res. Soc. Proc. 273, 1992) p. 417.Google Scholar
10. Raj, S.V., Mat. Sci. and Eng., A201, p. 229 (1995)Google Scholar
11. Nazmy, M. and Staubli, M., European Patent No. 425972B1, 1994.Google Scholar
12. Nazmy, M., Noseda, C., Sauthoff, G., Zeumer, B. and Anton, D., High-Temperature Ordered Intermetallic Alloys VI, edited by Horton, J.A., Baker, I., Hanada, S., Noebe, R.D. and Schwartz, D.S. (Mater. Res. Soc. Proc. 364, 1994, p1333)Google Scholar
13. Niihara, K., Morena, R. and Hasselman, D.P.H., J. of Mat. Sci. Letters, 1, p. 13 (1982).Google Scholar
14. Davidson, D.L., Chan, K.S. and Anton, D.L., Metall. Trans. A., 27A, p3007 (1996)Google Scholar
15. Subramanian, P.R., Mendiratta, M.G. and Dimiduk, D., High Temperature Suicides and Refractory Alloys, edited by Briant, C.L., Petrovic, J.J., Bewlay, B.P., Vasudevan, A.K. and Lipsitt, H.A. (Mater. Res. Soc. Proc. 322, 1993) p. 491 Google Scholar