Hostname: page-component-76fb5796d-45l2p Total loading time: 0 Render date: 2024-04-26T18:26:58.162Z Has data issue: false hasContentIssue false

Low-Temperature Direct-Oxidation of Si Using Activated Oxygen Generated by Tungsten Catalytic Reaction

Published online by Cambridge University Press:  10 February 2011

Manabu Kudo
Affiliation:
JAIST(Japan Advanced Institute of Science and Technology) Ishikawa 923-1292, Japan, mkudou@jaist.ac.jp
Akira Izumi
Affiliation:
JAIST(Japan Advanced Institute of Science and Technology) Ishikawa 923-1292, Japan, mkudou@jaist.ac.jp
Hideki Matsumura
Affiliation:
JAIST(Japan Advanced Institute of Science and Technology) Ishikawa 923-1292, Japan, mkudou@jaist.ac.jp
Get access

Abstract

Ultra-thin silicon dioxide films can be formed at temperatures as low as 220°C by direct oxidation of Si, using active oxygen species generated by tungsten catalytic reaction in a catalytic chemical vapor deposition (Cat-CVD) system. The structural and electrical properties of such a films are investigated. It is found that the density of Si atoms in intermediate oxidation states and the density of films determined from etch rate in dilute HF solution were comparable to those of the films by a conventional thermal oxidation at 900°C. The electrical properties, breakdown electric field and leakage current were also comparable to those of thermally oxidized films.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Matsumura, H. and Tachibana, H., Appl. Phys. Lett. 47, 833 (1985).Google Scholar
2.Matsumura, H., Jpn. J. Appl. Phys. 37, 3175 (1997).Google Scholar
3.Izumi, A. and Matsumura, H., Appl. Phys. Lett. 47, 833 (1997).Google Scholar
4.Izumi, A., Masuda, A. and Matsumura, H., Thin Solid Films, 343/344, 528 (1999).Google Scholar
5.Kern, W and Poutinen, D. A., RCA Rev. 31, 187 (1970).Google Scholar
6.Himpsel, F. J., McFeely, F. R., Taleb-Ibrahimi, A., and Yarmoff, J. A., Phys. Rev. B, 38, 6084 (1988).Google Scholar
7.Deal, B. E. and Grove, A. S., J. Appl. Phys., 36, 3770 (1965).Google Scholar
8.Hollinger, G. and Himpsel, F. J., Appl. Phys. Lett. 44, 93 (1984).Google Scholar
9.Aiba, T., Yamauchi, K., Shimizu, Y., Tate, N., Katayama, M., and hattori, T., Jpn. J. Appl. Phys. 34, 707 (1995).Google Scholar