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Linear and Nonlinear Optical Properties of Processable Polymeric Materials

Published online by Cambridge University Press:  25 February 2011

Toshikuni Kaino ,
Satoru Tomaru ,
Takashi Kurihara  and
Michiyuki Amano
Toshikuni Kaino
Affiliation:
NTT Optoelectronics Laboratories, Tokai, Ibaraki 319–11, Japan
Satoru Tomaru
Affiliation:
NTT Optoelectronics Laboratories, Tokai, Ibaraki 319–11, Japan
Takashi Kurihara
Affiliation:
NTT Optoelectronics Laboratories, Tokai, Ibaraki 319–11, Japan
Michiyuki Amano
Affiliation:
NTT Optoelectronics Laboratories, Tokai, Ibaraki 319–11, Japan
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Abstract

Linear and nonlinear optical (NLO) polymeric materials with good processabilities are discussed. An azo-dye substituted copolymer (3RNO2, nitro-terminated diazo dye) are investigated. The polymer film was found to be transparent and attenuation loss was less than 2 dB/cm. The χ(3) of 3RNo2 reaches 5×10−11 esu in the near-resonant region. With polymers where the dye molecules are introduced into the polymer backbone (a main chain polymer), a χ(3) larger than 10−11 esu is obtained even in a monoazo dye introduced polymer. A new molecular crystal, symmetrically substituted benzylidene-aniline compound, SBAC for short, are also successfully polymerized (introduced into a polymer main chain) and their χ(3) values are revealed to be around 1010 esu in the near-resonant wavelength region. The optical transmission of these polymers is also investigated and revealed to be around 2 dB/cm. With poly(arylene vinylene), a certain population of χ-conjugation length will induce enhancement of the resonant χ(3) of the polymers. The polymer can be used to fabricate channel waveguides with the photo-bleaching technique.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 179
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Chemla, D. S.; Zyss, J. Eds., Nonlinear Optical Properties of Organic Molecules and Crystals; (Academic Press, New York, 1987)Google Scholar
2. Heeger, A. J., Moses, D. and Sinclair, M., Synth. Met., 15, 95 (1986)Google Scholar
3. Beratan, D.N., Onuchic, J. N. and Perry, J.W., J. Phys. Chem., 91 2695 (1987)Google Scholar
4. Matsumoto, S., Kurihara, T., Kubodera, K. and Kaino, T., Appl. Phvs. Lett, 51, 1 (1987)Google Scholar
5. Kaino, T., Kubodera, K., Tomaru, S., Kurihara, T., Saito, S., Tsutsui, T. and Tokito, S., Electron. Lett., 23, 1095 (1987)Google Scholar
6. Kubodera, K. and Kaino, T., Nonlinear Optics of Organics and Semiconductors, edited by Kobayashi, T., (Springer-Verlag: Berlin, 1989) p 163 Google Scholar
7. Meredith, G. R., Buchalter, B., Hanzlik, C., J. Chem. Phys., 78, 1533 (1983)Google Scholar
8. Matsumoto, S., Kubodera, K., Kurihara, T. and Kaino, T., in Nonlinear Optics gf Organics and Semiconductors, edited by Kobayashi, T., (Springer-Verlag: Berlin, 1989) p236 Google Scholar
9 . Amano, M.; Kaino, T. Chem. Phys. Lett., 170, 515(1990)Google Scholar
10. Barzoukas, M.; Fremaux, P.; Josse, D.; Kajzer, F.; Zyss, J.; in Nonlinear optical Properties of Polymers, edited by Heeger, A.J., Orenstein, J. and Ulrich, D.R., (Material Research Society: Pittsburgh, 1988) p171 Google Scholar
11. Torruellas, W. E., Zanoni, R., Stegeman, G. I., Mohlmann, G. R., Erdhuisen, E. W. P. and Horsthuis, W. H. G., J. Chem. Phys., 94, 6851 (1991)Google Scholar
12. Matsumoto, S., Kurihara, T., Kubodera, K. and Kaino, T., Mol. Cryst. Liq. Cryst., 182A, 115 (1990)Google Scholar
13. Kaino, T., Amano, M. and Shuto, Y., Proc. 5th TOYOTA Conf., edited by Miyata, S. (Springer, to be published, 1992)Google Scholar
14. Spangler, C. W., Hall, T. J., Havelka, K. O., Polis, D. W., Sapochak, L. S. and Dalton, L. R., SPIE, 1337. 125(1990)Google Scholar
15. Rustagi, K. C. and Ducuing, K. C., Opt. Commun., 10, 258 (1974)Google Scholar
16. Kurihara, T., Mori, Y., Ooba, N., Tomaru, S., and Kaino, T., J. Appl. Phys., 70, 17 (1991)Google Scholar
17. Mori, Y., Kurihara, T., Kaino, T. and Tomaru, S., Jpn. J. Appl. Phys., to be published.Google Scholar
18. Tomaru, S., Kurihara, T., Ooba, N., Mori, Y., Shuto, Y. and Kaino, T., Polym. Preprints Jpn., 40 3618 (1991)Google Scholar
19. Kurihara, T., Mori, Y., kaino, T., Murata, H., Takada, N., Tsutsui, , and Saito, S., Chem. Phys. Lett, 183, 534 (1991)Google Scholar