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Laser Direct-Write Of Alkaline Microbatteries

Published online by Cambridge University Press:  11 February 2011

Craig B. Arnold  and
Alberto Piqué
Craig B. Arnold
Affiliation:
Materials Science and Technology Division, Naval Research Laboratory, Washington, DC 20375, USA
Alberto Piqué
Affiliation:
Materials Science and Technology Division, Naval Research Laboratory, Washington, DC 20375, USA
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Abstract

We are developing a laser engineering approach to fabricate and optimize various types of alkaline microbatteries. Microbattery cells are produced using a laser forward transfer process that is compatible with the materials required to make the anode, cathode, separator and current collectors. The use of an ultraviolet transfer laser (wavelength = 355 nm, 30 ns FWHM) enables other operations such as surface processing, trimming and micromachining of the transferred materials and substrate and is performed in situ. Such multi-capability for adding, removing and processing material is unique to this direct-write technique and provides the ability to laser pattern complicated structures needed for fabricating complete microbattery assemblies. In this paper, we demonstrate the production of planar zinc-silver oxide alkaline cell by laser direct-write under ambient conditions. The microbattery cells exhibit 1.5–1.6 V open circuit potentials, as expected for the battery chemistry and show flat discharge behavior under constant current loads.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 758: Symposium LL – Rapid Prototyping Technologies , 2002 , LL3.8
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1. Harb, J. N., LaFollette, R. M., Selfridge, R. H., and Howell, L. L., J. Power Sources 104, 46 (2002).Google Scholar
2. Koeneman, P. B., Busch-Vishniac, I. J., and Wood, K. L., J. Microelectromech. Sys. 6, 355 (1997).Google Scholar
3. Balkanski, M., Sol. Energy Mater. Sol. Cells 62, 21 (2000).Google Scholar
4. Bates, J. B., Dudney, N. J., Lubben, D. C., Gruzalski, G. R., Kwak, B. S., Yu, X., and Zuhr, R. A., J. Power Sources 54, 58 (1995).Google Scholar
5. Bates, J. B., Dudney, N. J., Neudecker, B., Ueda, A., and Evans, C. D., Solid State Ionics 135, 33 (2000).Google Scholar
6. Humble, P. H., Harb, J. N., and LaFollette, R., J. Electrochem. Soc. 148, A1357 (2001).Google Scholar
7. LaFollette, R. M., Harb, J. N., and Humble, P., in The Sixteenth Annual Battery Conference on Applications and Advances, IEEE, edited by Das, R. S. L. and Frank, H. (IEEE, Piscataway, NJ, 2001), pp. 349–354.Google Scholar
8. Swider-Lyons, K. E., Piqué, A., Arnold, C. B., and Wartena, R. C., in Electroactive Polymers and Rapid Prototyping, edited by Chrisey, D. B. and Danforth, S. C. (Materials Research Society, Pittsburgh, PA, 2002), Vol. 689, pp. 265–275.Google Scholar
9. Swider-Lyons, K. E., Piqué, A., Arnold, C. B., and Wartena, R. C., in The Encyclopedia of Materials Science and Technology, edited by Bushcow, K. H. J., Cahn, R. W., Flemings, M. C., Ilschner, B., Kramer, E. J., and Mahajan, S. (Pergamon, New York, 2002).Google Scholar
10. Chrisey, D. B., McGill, R. A., and Piqué, A., U.S. Patent No. 6,177,151 (1999).Google Scholar
11. Piqué, A., Chrisey, D. B., Fitz-Gerald, J. M., McGill, R. A., Auyeung, R. C. Y., Wu, H. D., Lakeou, S., Nguyen, V., Chung, R., and Duignan, M., J. Mater. Res. 15, 1872 (2000).Google Scholar
12. Chrisey, D. B., Piqué, A., Fitz-Gerald, J., Auyeung, R. C. Y., McGill, R. A., Wu, H. D., and Duignan, M., Appl. Surf. Sci. 154–155, 593 (2000).Google Scholar
13. Arnold, C. B., Wartena, R. C., Swider-Lyons, K. E., and Piqué, A., Electrochem, J.. Soc. (in press).Google Scholar
14. Arnold, C. B., Wartena, R. C., Pratap, B., Swider-Lyons, K. E., and Piqué, A., in Electroactive Polymers and Rapid Prototyping, edited by Chrisey, D. B. and Danforth, S. C. (Materials Research Society, Pittsburgh, PA, 2002), Vol. 689, pp. 275–280.Google Scholar
15. Piqué, A., Arnold, C. B., Wartena, R. C., Weir, D. W., Pratap, B., Swider-Lyons, K. E., Kant, R. A., and Chrisey, D. B., in Third International Symposium on Laser Precision Microfabrication (SPIE, Bellingham, WA, In Press).Google Scholar
16. Megahed, S. A., Passaniti, J., and Springstead, J. C., in Handbook of Batteries, edited by Linden, D. and Reddy, T. B. (McGraw-Hill, New York, 2002), Chap. 12, pp. 12.1–12.17.Google Scholar