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In-Situ Preparation of TiC/Al2O3, TiN/Al2O3 and TiN/AIN Composites From Alkoxide-Derived Precursors

Published online by Cambridge University Press:  25 February 2011

Zhiping Jiang  and
Wendell E. Rhine
Zhiping Jiang
Affiliation:
Ceramics Processing Research Laboratory Massachusetts Institute of Technology, Cambridge, MA 02139
Wendell E. Rhine
Affiliation:
Ceramics Processing Research Laboratory Massachusetts Institute of Technology, Cambridge, MA 02139
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Abstract

The reaction between furfuryl alcohol (FuOH) and the hydrolysis product of a mixture of Ti(O-n-Bu)4 and Al(O-sec-Bu)3 (AI:Ti=1:1) resulted in the formation of soluble polymeric solids. Pyrolysis of these polymers in argon yielded TiC/A2O3 composite at 1250 °C. When these polymers were pyrolyzed in ammonia, TiN/AI2O3 or TiN/AIN composite was formed. All these composites showed fine microstructure and excellent homogeneity. Furthermore, the structure and pyrolysis chemistry of these polymeric precursors as well as the microstructure of the pyrolysis products were studied by means of FTIR, TGA, XRD, SEM, TEM, STEM, Auger, elemental analyses etc.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 249: Symposium Q – Synthesis and Processing of Ceramics: Scientific Issues , 1991 , 45
Copyright
Copyright © Materials Research Society 1992

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References

REFERENCES

1. Mukerji, J. and Biswas, S.K., J. Am. Ceram. Soc. 73, 142 (1990).CrossRefGoogle Scholar
2. Mathers, J.P., Forester, T.E. and Wood, W.P., Ceram. Bull. 68, 1330 (1989).Google Scholar
3. Nagano, T., Kato, H., Wakai, F., J. Am. Ceram. Soc. 74, 2258 (1991).CrossRefGoogle Scholar
4. Gallo, T., Cambria, F., Greco, C., Simms, B. and Valluzzi, R., “Metal Carbide from Alkoxides and Modified Alkoxides” Final Program and Abstract, 1990 Fall MRS Meeting, P. 439.Google Scholar
5. Jiang, Z. and Rhine, W.E., “Preparation of TiN and TiC from a Polymeric Precursor” to be published in Chem. Mater.Google Scholar
6. Kamiya, K.; Yoko, T.; Bessho, M., J. Mater. Sci. 22, 937 (1987).CrossRefGoogle Scholar
7. Keddie, J.L., Li, J., Mayer, J.W. and Giannnelis, E.P., J. Am. Ceram. Soc. 74, 2937 (1991).CrossRefGoogle Scholar
8. van, F.K. Dijen and Pluijmakers, J., J. Eur. Ceram. Soc. 5, 385 (1989).Google Scholar