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Implementation of CVD Diamond Growth Methods for Selective and Efficient Formation of Color-Centers in Diamond

  • Stefano Gay (a1), Giacomo Reina (a1), Ilaria Cianchetta (a1), Emanuela Tamburri (a1), Mariglen Angjellari (a1), Maria Letizia Terranova (a1) and Silvia Orlanducci (a1)...


We report here on the chemical methodologies that are being settled in our labs for the insertion in diamond of foreign atoms and consequent creation of fluorescent defects. The inclusion of Si, Cr, Ge, able to produce color centers, is directly obtained during the process of diamond synthesis by means of a CVD technique. The deposition of the diamond films takes place on substrates of different nature, treated following procedures specifically settled to control the insertion of the different species. The photoluminescence emission from a series of diamond samples grown on different substrates (Si, Ge and Ti) has been investigated and is discussed with reference to the morphological/structural features of the diamond phase and to the experimental procedures adopted for substrate preparation.



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1. Zaitsev, A. M. (2000). Vibronic spectra of impurity-related optical centers in diamond. Physical Review B, 61(19), 12909.10.1103/PhysRevB.61.12909
2. Beha, K., Batalov, A., Manson, N. B., Bratschitsch, R., & Leitenstorfer, A. (2012). Optimum photoluminescence excitation and recharging cycle of single nitrogen-vacancy centers in ultrapure diamond. Physical review letters, 109(9), 097404 10.1103/PhysRevLett.109.097404
3. Kennedy, T. A., Colton, J. S., Butler, J. E., Linares, R. C., & Doering, P. J. (2003). Long coherence times at 300 K for nitrogen-vacancy center spins in diamond grown by chemical vapor deposition. Applied Physics Letters, 83(20), 41904192.10.1063/1.1626791
4. Sternschulte, H., Thonke, K., Sauer, R., Münzinger, P. C., & Michler, P. (1994). 1.681-eV luminescence center in chemical-vapor-deposited homoepitaxial diamond films. Physical Review B, 50(19), 14554.10.1103/PhysRevB.50.14554
5. Neu, E., Steinmetz, D., Riedrich-Möller, J., Gsell, S., Fischer, M., Schreck, M., & Becher, C. (2011). Single photon emission from silicon-vacancy colour centres in chemical vapour deposition nano-diamonds on iridium. New Journal of Physics, 13(2), 025012.10.1088/1367-2630/13/2/025012
6. Aharonovich, I., Castelletto, S., Simpson, D. A., Stacey, A., McCallum, J., Greentree, A. D., & Prawer, S. (2009). Two-level ultrabright single photon emission from diamond nanocrystals. Nano letters, 9(9), 31913195.10.1021/nl9014167
7. Aharonovich, I., Castelletto, S., Simpson, D. A., Greentree, A. D., & Prawer, S. (2010). Photophysics of chromium-related diamond single-photon emitters. Physical Review A, 81(4), 043813.10.1103/PhysRevA.81.043813
8. Neu, E., Agio, M., & Becher, C. (2012). Photophysics of single silicon vacancy centers in diamond: implications for single photon emission. Optics express, 20(18), 1995619971.10.1364/OE.20.019956
9. Aharonovich, I., Castelletto, S., Simpson, D. A., Su, C. H., Greentree, A. D., & Prawer, S. (2011). Diamond-based single-photon emitters. Reports on progress in Physics, 74(7), 076501.10.1088/0034-4885/74/7/076501
10. Terranova, M. L., Piccirillo, S., Sessa, V., Rossi, M., & Cappuccio, G. (1999). A New CVD Route for the Synthesis of Composite Diamond-Based Materials. Chemical Vapor Deposition, 5(3), 101105.10.1002/(SICI)1521-3862(199906)5:3<101::AID-CVDE101>3.0.CO;2-W
11. Williams, O. A., Douhéret, O., Daenen, M., Haenen, K., Ōsawa, E., & Takahashi, M. (2007). Enhanced diamond nucleation on monodispersed nanocrystalline diamond. Chemical Physics Letters, 445(4), 255258.10.1016/j.cplett.2007.07.091
12. Daenen, M., Williams, O. A., D'Haen, J., Haenen, K., & Nesládek, M. (2006). Seeding, growth and characterization of nanocrystalline diamond films on various substrates. physica status solidi (a), 203(12), 30053010.10.1002/pssa.200671122
13. Yang, P. C., Zhu, W., & Glass, J. T. (1993). Nucleation of oriented diamond films on nickel substrates. Journal of materials research, 8(08), 17731776.10.1557/JMR.1993.1773
14. Cianchetta, I., Tomellini, M., Tamburri, E., Gay, S., Porchetta, D., Terranova, M. L., & Orlanducci, S. (2014). Can a metal nanoparticle based catalyst drive the selective growth of bright SiV color centers in CVD diamonds?. Journal of Materials Chemistry C, 2(45), 96669673.10.1039/C4TC01164C
15. Cianchetta, Ilaria (2012) “Optical properties of synthetic diamonds and nanodiamonds from synthesis to characterization” PhD dissertation University of Rome Tor Vergata, Italy



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