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Hydrogen and Hydrogen-Related Defects in CVD Diamond

Published online by Cambridge University Press:  10 February 2011

K. M. McNamara Rutledge*
Affiliation:
Department of Chemical Engineering, Worcester Polytechnic Institute Worcester, MA, USA
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Abstract

Hydrogen is a detrimental impurity in many chemical vapor deposited (CVD) materials, particularly those involved in electronic or optical applications. For example, active hydrogen defects have been observed in materials such as silicon, Si, gallium arsenide, GaAs, and diamond, C, thin films. Hydrogen and its related defects can be identified, quantified, and observed using magnetic resonance techniques. These techniques allow a unique quantitative, non-destructive view of hydrogen in the solid-state. Nuclear magnetic resonance (NMR) is used to study hydrogenated defects directly, while electron paramagnetic resonance (EPR) is used to observe hydrogen associated with paramagnetic defects. These observations can enhance our understanding of the effects of hydrogen incorporation on the properties of such materials.

Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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