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Highly dispersed metal-clusters and -colloids for the preparation of active liquid-phase hydrogenation-catalysts

  • Helmut Bönnemann (a1), Werner Brijoux (a1), Rainer Brinkmann (a1), Eckard Dinjus (a1), Rainer Fretzen (a1), Thomas Joußen (a1) and Barbara Korall (a1)...

Summary

A comparison of the activities of conventionally precipitated metals on charcoal, deposited organometallic clusters and metal colloids for liquid-phase hydrogenation has been made under standard conditions in order to assess the effect of particle size. The strong SMSI-effect known for TiO2-supports was simulated on charcoal by doping the surface with small amounts of Ti(0) and subsequent oxygenation.

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Highly dispersed metal-clusters and -colloids for the preparation of active liquid-phase hydrogenation-catalysts

  • Helmut Bönnemann (a1), Werner Brijoux (a1), Rainer Brinkmann (a1), Eckard Dinjus (a1), Rainer Fretzen (a1), Thomas Joußen (a1) and Barbara Korall (a1)...

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