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Hexathiapentacene Nanowires as Chemical Vapor Sensors

Published online by Cambridge University Press:  01 February 2011

Ting Gao
Affiliation:
ting.gao@tycoelectronics.com, Tyco Electronics Corporation, Polymers, Ceramics and Technical Services Laboratories, Menlo Park, California, United States
Edgardo Garcia-Berrios
Affiliation:
edgardog@caltech.edu, California Institute of Technology, Division of Chemistry and Chemical Engineering, Pasaneda, California, United States
Alejandro L Briseno
Affiliation:
abriseno@mail.pse.umass.edu, Universtiy of Massachusetts, Polymer Science and Engineering, Amherst, Massachusetts, United States
Jian Wang
Affiliation:
jian.wang@tycoelectronics.com, Tyco Electronics Corporation, Polymers, Ceramics and Technical Services Laboratories, Menlo Park, California, United States
Richard McConville
Affiliation:
rmcconvi@tycoelectronics.com, Tyco Electronics Corporation, Polymers, Ceramics and Technical Services Laboratories, Menlo Park, California, United States
Mark W Ellsworth
Affiliation:
mellswor@tycoelectronics.com, Tyco Electronics Corporation, Polymers, Ceramics and Technical Services Laboratories, Menlo Park, California, United States
Ryan W Dupon
Affiliation:
rdupon@tycoelectronics.com, Tyco Electronics Corporation, Polymers, Ceramics and Technical Services Laboratories, Menlo Park, California, United States
Nathan Lewis
Affiliation:
nslewis@caltech.edu, California Institute of Technology, Division of Chemistry and Chemical Engineering, Pasaneda, California, United States
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Abstract

Semiconducting hexathiapentacene (HTP) single–crystal nanowires were synthesized using a simple solution-phase route. Quartz Crystal Microbalance and complex resistance measurements were employed to investigate the sensing properties of an HTP nanowire to analytes including acid, amine, and hydrocarbon vapors. Cole-Cole plots (0.01Hz-4 MHz) of measured impedance spectra, modeled using equivalent circuits, were used to resolve the effects of adsorption and charge migration.

Type
Research Article
Copyright
Copyright © Materials Research Society 2010

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