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G-band Raman Spectra of Isolated Single Wal Carbon Nanotubes: Diameter and Chiraity Dependence

  • A. Jorio (a1), A. G. Souza Filho (a1) (a2), G. Dresselhaus (a1), M. S. Dresselhaus (a1), A. K. Swan (a3), M. S. Ünlü (a3), B. B. Goldberg (a3), M. A. Pimenta (a4), J. H. Hafner (a5), C. M. Lieber (a5) and R. Saito (a6)...

Abstract

We present results from resonant Raman spectroscopy on the graphite-like G band by measuring Raman spectra on isolated single wal carbon nanotubes (SWNTs). We discuss the G-band lineshape dependence on nanotube diameter and chirality, as well as polarization studies related to the antenna effect. Symmetry selection rules, dipolar and multipolar antenna behaviors are discussed. Spectra at the single nanotube level are related to spectra observed from SWNT bundles.

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