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Fermi Surface Study of Organic Metals (Bedt-TTF)2X

Published online by Cambridge University Press:  25 February 2011

M. Tokumoto ,
A. G. Swanson ,
J. S. Brooks ,
C. C. Agosta ,
S. T. Hannahs ,
N. Kinoshita ,
H. Anzai ,
M. Tamura ,
H. Tajima  and
H. Kuroda
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M. Tokumoto
Affiliation:
Electrotechnical Laboratory, Tsukuba, Ibaraki 305, Japan
A. G. Swanson
Affiliation:
Department of Physics, Boston University, Boston, MA 02215, U. S. A.
J. S. Brooks
Affiliation:
Department of Physics, Boston University, Boston, MA 02215, U. S. A.
C. C. Agosta
Affiliation:
Francis Bitter National Magnet Laboratory, MIT, Cambridge, MA 02138., U. S. A.
S. T. Hannahs
Affiliation:
Francis Bitter National Magnet Laboratory, MIT, Cambridge, MA 02138., U. S. A.
N. Kinoshita
Affiliation:
Electrotechnical Laboratory, Tsukuba, Ibaraki 305, Japan
H. Anzai
Affiliation:
Electrotechnical Laboratory, Tsukuba, Ibaraki 305, Japan
M. Tamura
Affiliation:
Department of Chemistry, Faculty of Science, The University of Tokyo, Tokyo 113, Japan
H. Tajima
Affiliation:
Department of Chemistry, Faculty of Science, The University of Tokyo, Tokyo 113, Japan
H. Kuroda
Affiliation:
Department of Chemistry, Faculty of Science, The University of Tokyo, Tokyo 113, Japan
A. Ugawa
Affiliation:
Department of Chemistry, Faculty of Science, The University of Tokyo, Tokyo 113, Japan
K. Yakushi
Affiliation:
Institute for Molecular Science, Okazaki 444, Japan
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Abstract

Observations of Shubnikov-de Haas(SdH) and de Haas-van Alphen(dHvA) oscillations in organic metals (BEDT-TTF)2X, with X=KHg(SCN)4, θ-I3 and β″-AuBr2. are reported. In KHg(SCN)4 salt, in addition to the SdH oscillations with fundamental frequency of 670 T corresponding to about 16% of the first Brillouin zone(FBZ), we observed splitting of each SdH peak which we ascribed to “spin-splitting” We have also found that the ground state of this salt is not a simple metal but has some magnetic character. In θ-l3 salt we have succeeded in an observation of dHvA oscillations for the first time. We observed a “saw-tooth” dHvA oscillation characteristic to a highly two-dimensional and extraordinary clean electronic system. In addition to the fundamental frequency of 4170 T corresponding to 50.4 % of the FBZ and its higher harmonics, we observed an oscillation with lower frequency of 730 T corresponding to about 8.8 % of the FBZ. A new Fermi surface topology for θ-l3 salt is proposed based on the analysis of the dHvA effect. In β″-AuBr2, we observed complex dHvA oscillations, which can be explained in terms of the mixing of two fundamental frequencies of 47 and 268 T, suggesting the presence of very small pockets corresponding to 0.6 and 2.9 % of the FBZ.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 247: Symposium N – Electrical, Optical, and Magnetic Properties of Organic Solid State Materials , 1992 , 515
Copyright
Copyright © Materials Research Society 1992

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References

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