Hostname: page-component-76fb5796d-2lccl Total loading time: 0 Render date: 2024-04-26T05:43:14.018Z Has data issue: false hasContentIssue false

Fabrication of Polycrystalline Si Thin Film for Solar Cells

Published online by Cambridge University Press:  15 February 2011

M. Tanaka
Affiliation:
New Materials Research Center, Sanyo Electric Co., Ltd. 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
S. Tsuge
Affiliation:
New Materials Research Center, Sanyo Electric Co., Ltd. 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
S. Kiyama
Affiliation:
New Materials Research Center, Sanyo Electric Co., Ltd. 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
S. Tsuda
Affiliation:
New Materials Research Center, Sanyo Electric Co., Ltd. 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
S. Nakano
Affiliation:
New Materials Research Center, Sanyo Electric Co., Ltd. 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
Get access

Abstract

The a-Si/poly-Si thin film tandem solar cell is a promising candidate for low-cost solar cells. We have conducted R&D on poly-Si thin film using the Solid Phase Crystallization (SPC) method from amorphous silicon (a-Si). To improve the film quality of SPC poly-Si, we have developed a new SPC method called the partial doping method. This method features two stacked starting a-Si layers, a P-doped layer and a non-doped layer. Nucleation occurs in the P-doped layer, and the non-doped layer is the crystal growth layer. For the nucleation layer, we developed a Si film with a unique structure, which features relatively large crystallites (-1000A) embedded in a matrix of amorphous tissue. By combining these technologies, a conversion efficiency of 9.2% was obtained for poly-Si thin-film solar cells. For further improvement in the conversion efficiency, based on the concept of “independent control of nucleation and crystal growth”, it is necessary to combine the best fabrication methods for each layer. A high conversion efficiency of more than 12% was found possible by using the CVD method and a new back surface reflection structure.

Type
Research Article
Copyright
Copyright © Materials Research Society 1997

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Kuwano, Y., Imai, T., Ohnishi, M. and Nakano, S., Proc. of 14th IEEE Photovol. Spec. Conf., San Diego (1980) 1408.Google Scholar
2.Kuwano, Y., Ohnishi, M., Tsuda, S., Nakashima, Y. and Nakamura, N., Jpn. J. Appl. Phys., 53 (1982)5273.Google Scholar
3.Nakano, S., Matsuoka, T., Kiyama, S., Kawata, H., Nakamura, N., Nakashima, Y., Tsuda, S., Nishiwaki, H., Ohnishi, M., Nagaoka, I. and Kuwano, Y., Jpn. J. Appl. Phys., 25(1986) 1936.Google Scholar
4.Tsuda, S., Takahama, T., Isomura, M., Tarui, H., Nakashima, Y., Hishikawa, Y., Nakamura, N., Matsuoka, T., Nishiwaki, H., Nakano, S., Ohnishi, M. and Kuwano, Y., Jpn. J. Appl. Phys., 26 (1987)33.Google Scholar
5.Kuwano, Y. and Ohnishi, M., Proc. 9th Int. Conf. Amorphous & Liquid Semicond., Grenoble (1981) C41155.Google Scholar
6.Wakisaka, K., Tanaka, M., Isomura, M., Haku, H., Kiyama, S. and Tsuda, S., Technical Digest International PVSEC-9, Miyazaki (1996) 583.Google Scholar
7.Kuriyama, H., Nohda, T., Aya, Y., Kuwahara, T., Wakisaka, K., Kiyama, S. and Tsuda, S., Jpn. J. Appl. Phys., 33 (1994) 5657.Google Scholar
8.Takakura, H., Miyagi, K., Kanata, T., Okamoto, H. and Hamakawa, Y., Proc. of 4th Int. Photovoltaic Science & Engineering Conf. (1989) 403.Google Scholar
9.Taguchi, M., Tanaka, M., Matsuyama, T., Matsuoka, T., Tsuda, S., Nakano, S., Kishi, Y. and Kuwano, Y., Technical Digest of 5th International PVSEC (1990) 689.Google Scholar
10.Matsuyama, T., Wakisaka, K., Kameda, M., Tanaka, M., Matsuoka, T., Tsuda, S., Nakano, S., Kishi, Y. and Kuwano, Y., Jpn. J. Appl. Phys., 29 (1990) 2327.Google Scholar
11.Staebler, D.L. and Wronski, C.R., Appl. Phys. Lett., 31 (1977) 292.Google Scholar
12.Matsuyama, T., Tanaka, M., Tsuda, S., Nakano, S. and Kuwano, Y., Jpn. J. Appl. Phys. 32, (1993) 3720.Google Scholar
13.Seto, John Y. W., J. Appl. Phys., 46 (1975) 5247.Google Scholar
14.Shimada, T., Katayama, Y., Nakagawa, K., Matsubara, H., Migitaka, M. and Maruyama, E., J. Non-Cryst. Solids., 59&60 (1983) 783.Google Scholar
15.Matsuda, A., J. Non-Cryst. Solids., 59&60 (1983) 767.Google Scholar