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Fabrication of Nano-Structured Gold Arrays by Guided Self-assembly for Plasmonics

  • Xiaoli V. Li (a1), Clelia A. Milhano (a2), Robin M. Cole (a3), Phil N. Bartlett (a4), Jeremy J. Baumberg (a5) and Cornelis H. de Groot (a6)...


Gold inverse spherical nanoscale voids have been fabricated in linear arrays for directional plasmon measurements in the visible spectral range. We show that by KOH anisotropic etching in Si, we are able to make V-grooves in which latex spheres of the order of 500 nm self-assemble with largely defect-free cubic symmetry. Both single layer and multilayer assembly in a face-centered close-packed (FCC) lattice can be achieved by varying the width of the trenches. This template is subsequently used for electrodeposition of gold to create the inverse spherical nanovoids.



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1. Bae, C., Shin, H., and Moon, J., Chemistry of Materials, 19, 1531 (2007).
2. Ye, J., Zentel, R., Arpiainen, S., Ahopelto, J., Jonsson, F., Romanov, S.G., and SotomayorTorres, C.M., Langmuir, 22, 7378 (2006).
3. Nagayama, K., Colloids Surfaces A, 109, 363 (1996).
4. Donselaar, L.N., Philipse, A.P., and Suurmond, J., Langmuir, 13(23):60186025, 1997.
5. Denkov, N.D., Velev, O.D., Kralchevsky, P.A, Ivanov, I.B., Yoshimura, H., and Nagayama, K., Langmuir, 8:31833190, 1992.
6. Hulteen, J. C. and Duyne, R.P. van, J. Vac. Sci. Technol. A, 13:15531558, 1995.
7. Kalsin, A. M., Fialkowski, M., Paszewski, M., Smoukov, S. K., Bishop, K. J. M., and Grzybowski, B. A., Science, 312(5772):420424, 2006.
8. Blaaderen, Alfons van, Ruel, Rene, and Wiltzius, Pierre, Nature, 386:321324, 1997.
9. Kiziroglou, M. E., Li, X., Gonzalez, D. C., Groot, C. H. de, Zhukov, A. A., Groot, P. A. J. de, and Bartlett, P. N., J. Appl. Phys., 100:113720113725, 2006.
10. Conway, J. H. and Sloane, N. J. A.. Sphere packings, lattices and groups. Springer-Verlag, 1988.
11. .Ozin, G. A. and Yang, S. M., Advanced Functional Materials, 11:95104, 2001.
12. Yang, San Ming and Ozin, Geoffrey A., Chem. Commun., pages 25072508, 2000.
13. Yadong, Yin, Yu, Lu, Byron, Gates, and Xia, Y., J. Am. Chem. Soc., 123, 8718 (2001).
14. Yadong, Yin, Zhi-Yuan, Li, and Xia, Younan, Langmuir, 19:622631, 2003.
15. Xia, Younan; Yin, Yadong; Lu, Yu, Advanced Functional Materials, 13, 907, 2003.
16. Kelf, T. A., Sugawara, Y., Cole, R. M., Baumberg, J. J., Abdelsalam, M. E., Cintra, S., Mahajan, S., Russell, A. E., and Bartlett, P. N., Physical Review B (Condensed Matter and Materials Physics), 74(24):245415, 2006.
17. Cole, R.M., Baumberg, J.J., GarciadeAbajo, F.J., Mahajan, S., Abdelsalam, M., and Bartlett, P.N., Nano Letters, 7(7):20942100, 2007.
18. Kiziroglou, M. E., Zhukov, A. A., Abdelsalam, M., Li, X., Groot, P. A. J. de, Bartlett, P. N., and Groot, C. H. de, IEEE Transactions on Magnetics, 41:26392641, 2005.
19. Kiziroglou, M. E., Zhukov, A. A., Li, X., Gonzalez, D. C., Groot, P. N. de, P. A. J. and , Bartlett, and Groot, C. H. de, Solid State Communications, 140:508513, 2006.



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