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Evolution of corrosion parameters in a buried pilot nuclear waste container in el Cabril

Published online by Cambridge University Press:  03 July 2014

Carmen Andrade
Affiliation:
Institute of Construction Science “Eduardo Torroja” (IETcc), CSIC, Serrano Galvache 4, 28033, Madrid, Spain.
Samuel Briz
Affiliation:
Institute of Construction Science “Eduardo Torroja” (IETcc), CSIC, Serrano Galvache 4, 28033, Madrid, Spain.
Javier Sanchez
Affiliation:
Institute of Construction Science “Eduardo Torroja” (IETcc), CSIC, Serrano Galvache 4, 28033, Madrid, Spain.
Pablo Zuloaga
Affiliation:
ENRESA (Spanish Agency for Management of Radioactive Wastes) Emilio Vargas, 7, 28043, Madrid, Spain.
Mariano Navarro
Affiliation:
ENRESA (Spanish Agency for Management of Radioactive Wastes) Emilio Vargas, 7, 28043, Madrid, Spain.
Manuel Ordoñez
Affiliation:
ENRESA (Spanish Agency for Management of Radioactive Wastes) Emilio Vargas, 7, 28043, Madrid, Spain.
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Abstract

Modern concrete has a record of good performance of around 120 years although there are structures in perfect conservation made with roman concrete (mixture of lime and natural pozzolans). El Cabril repository has a design life of 300-500 years and therefore, it should keep its integrity much longer than the back experience we have on reinforced concrete structures, which makes necessary a closer monitoring with time on the aging of concrete in real conditions. With this purpose, Enresa has designed in collaboration with IETcc and Geocisa the installation of permanent sensors in a pilot nuclear waste container in buried conditions. The sensors were installed in 1995 for monitoring corrosion parameters and have been working until present. The non-destructive tests (NDT) applied are based in electrochemical measurements (corrosion rate, corrosion potential, electrical resistivity, concrete strains, oxygen availability). Relations between the climatic influence, the buried depth and the corrosion parameters are also presented. The results indicate that temperature is a very relevant variable influencing the measurements. All the other parameters evolve according to seasonal changes. Values of activation energies of the resistivity changes are given although it seems more adequate to model the evolution with time by simply plotting the values registered at 20 ± 2 °C.

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Articles
Copyright
Copyright © Materials Research Society 2014 

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References

REFERENCES

Andrade, C., Martinez, I., Castellote, M., and Zuloaga, P., “Some principles of service life calculation of reinforcements and in situ corrosion monitoring by sensors in the radioactive waste containers of El Cabril disposal (Spain),” Journal of Nuclear Materials, vol. 358, pp. 8295, Nov 2006.CrossRefGoogle Scholar
Andrade, C., Rodriguez, J., Jimenez, F., Palacio, J., and Zuloaga, P., “Embedded sensors for concrete structures instrumentation,” in OECD-NEA Workshop on Instrumentation and Monitoring of Concrete Structures Brussels, ed Belgium, 2000.Google Scholar
Andrade, C. and Alonso, C., “Test methods for on-site corrosion rate measurement of steel reinforcement in concrete by means of the polarization resistance method,” Materials and Structures, vol. 37, pp. 623643, 2004.CrossRefGoogle Scholar
Andrade, C., Alonso, C., Gulikers, J., Polder, R., Cigna, R., Vennesland, O., et al. ., “Test methods for on-site corrosion rate measurement of steel reinforcement in concrete by means of the polarization resistance method,” Materials and Structures, vol. 37, pp. 623643, Nov 2004.CrossRefGoogle Scholar
Andrade, C., Sanchez, J., Fullea, J., Rebolledo, N., and Tavares, F., “On-site corrosion rate measurements: 3D simulation and representative values,” Materials and Corrosion, vol. 63, pp. 11541164, 2012.10.1002/maco.201206775CrossRefGoogle Scholar
Andrade, C. and González, J. A., “Quantitative measurements of corrosion rate of reinforcing steels embedded in concrete using polarization resistance measurements,” Materials and Corrosion, vol. 29, pp. 515519, 1978.CrossRefGoogle Scholar
Gowers, K. R. and Millard, S. G., “Measurement of concrete resistivity for assessment of corrosion severity of steel using Wenner technique,” Aci Materials Journal, vol. 96, pp. 536541, 1999.Google Scholar
Gjorv, O. E., Vennesland, O., and Elbusaidy, A. H. S., “Diffusion of dissolved-oxygen through concrete,” Materials Performance, vol. 25, pp. 3944, Dec 1986.Google Scholar
Naus, D. J., Johnston, M. W., Andrade, C., Ashar, H., Bittnar, Z., Breulet, H., et al. ., “RILEM TC 160-MLN: Methodology for life prediction of concrete structures in nuclear power plants - Progress report - August 1999,” Materials and Structures, vol. 33, pp. 98100, Mar 2000.Google Scholar
Clifton, J. R., “Predicting the service life of concrete,” Aci Materials Journal, vol. 90, pp. 611617, Nov-Dec 1993.Google Scholar
Rodriguez, J., Ortega, L. M., Aragoncillo, J., Izquierdo, D., and Andrade, C., Structural assessment methodology for residual life calculation of concrete structures affected by reinforcement corrosion vol. 16, 2000.Google Scholar
Zuloaga, P., Ordonez, M., Andrade, C., and Castellote, M., “Ageing management program for the Spanish low and intermediate level waste disposal and spent fuel and high-level waste centralised storage facilities,” in Amp 2010-International Workshop on Ageing Management of Nuclear Power Plants and Waste Disposal Structures. vol. 12, Lhostis, V., Philipose, K., Gens, R., and Galle, C., Eds., ed, 2011.Google Scholar
Koster, M., Hannawald, J., and Brameshuber, W., “Simulation of water permeability and water vapor diffusion through hardened cement paste,” Computational mechanics, vol. 37, pp. 163172, 2006.CrossRefGoogle Scholar
Raupach, M., “Results from laboratory tests and evaluation of literature on the influence of temperature on reinforcement corrosion,” in Corrosion of Reinforcement in Concrete: Monitoring, Prevention and Rehabilitation, Mietz, J., Elsener, B., and Polder, R., Eds., ed, 1998, pp. 920.Google Scholar