Skip to main content Accessibility help
×
Home

Enzyme-based Biohybrid Foams Designed for Biodiesel Production and Continuous Flow Heterogeneous Catalysis

  • Nicolas Brun (a1), Hervé Deleuze (a2) and Rénal Backov (a1)

Abstract

The one pot-synthesis and use of monolithic biohybrid foams in a continuous flow device reported inhere presents the advantages of covalent stabilization of the enzymes, together with a low steric hindrance between proteins and substrates, an optimized mass transport due to the interconnected macroporous network and a rather simplicity in regard of the column in-situ synthetic path. Those features, concerning transesterification (biodiesel production) enzyme- based catalyzed reaction, provide high enzymatic activity addressed with bio-hybrid catalysts bearing unprecedented endurance of continuous catalysis for a two months period of time.

Copyright

References

Hide All
1. Fukuda, H., Kondo, A., Noda, H., Journal of Bioscience and Bioengineering 92, 405 (2001).
2. Al-Widyan, M.I., Al-Shyoukh, A.O., Bioresource Technology 85, 253 (2002).
3. Nye, M.J., Williamson, T.W., Deshpande, S., Shrader, J.H., Snively, W.H., Yurkewich, T.P., French, C.R., J. Am. Oil Chem. Soc. 60, 1598 (1983).
4. Antczak, M.S., Kubiak, A., Antczak, T., Bielecki, S., Renewable Energy 34, 1185 (2009).
5. Klibanov, A. M., Science 219, 722 (1983).
6. Zhou, G., Chen, Y., Yan, S., Micro. Meso. Mater. 119, 223 (2009).
7. Wang, C. F., Zhou, G.W., Li, Y.J, Lu, N., Song, H.B., Zhang, L., Colloids § Surfaces A: Physicochemical and Engineering Aspects 406, 75 (2012)
8. Reetz, M. T., Zonta, A., Simplekamp, J., Biotechnology and Bioengineering 49, 527 (1996).
9. Wang, Z.J., Etienne, M., Quiles, F, G.W., Walcarius, A., Biosens. Bioel. 32, 111 (2012).
10. Chen, Y., Xiao, B., Chang, J., Fu, Y., Lv, P., Wang, X., Energy Conversion and Management 50 668 (2009).
11. Lozano, P., Garcia-Verdugo, E., Piamtongkam, R., Karbass, N., De Diego, T., Burguete, M. I., Luis, S. V., Iborra, J.L., Adv. Synth. Catal. 349, 1077 (2007).
12. Calleri, E., Temporini, C., Furlanetto, S., Loiodice, F., Fracchiolla, G., Massolini, G., Journal of Pharmaceutical and Biomedical Analysis 32, 715 (2003).
13. Mateo, C., Grazù, V., Palomo, J.M., Lopez-Gallego, F., Fernandez-Lafuente, R., Guisan, J.M., Nature Protocol 2, 1022 (2007).
14. Mateo, C., Fernandez-Lorente, G., Abian, O., Fernandez-Lafuente, R., Guisan, J.M., Biomacromolecule 1, 739 (2000).
15. Brun, N., Babeau-Garcia, A., Deleuze, H., Duran, F., Sanchez, C., Ostreicher, V., Backov, R., Chem. Mater. 22, 4555 (2010).
16. Rupley, J.A., Careri, G., Adv. Protein Chem. 41, 37 (1991).
17. Nie, K., Xie, F., Wang, F., Tan, T., J. Mol. Cat. B: Enzymatic 43, 142 (2006).
18. Halim, S.F.A., Kamaruddin, A. H., Fernando, W.J.N., Bioresource Technology 100, 710 (2009).
19. Royon, D., daz, M., Ellenrieder, G., Locatelli, S., Bioresource Technology 98, 648 (2007).
20. Backov, R., Soft Matter 2, 452 (2006).
21. Prouzet, E., Ravaine, S., Sanchez, C., Backov, R., New J. Chem. 32, 1284 (2008).
22. Ungureanu, S., Birot, M., Guillaumme, L., Deleuze, H., Babot, O., Achard, M.-F., Popa, M. I., Sanchez, C., Backov, R., Colloids § Surfaces A: Physicochemical and Engineering Aspects 360, 85 (2010).
23. Brun, N., Ungureanu, S., Deleuze, H., Backov, R., Chem. Soc. Rev. 40, 771 (2011).
24. Brun, N., Julian-Lopez, B., Hesemann, P., Laurent, G., Deleuze, H., Sanchez, C., Achard, M.-F., Backov, R., Chem. Mater 20, 7117 (2008).
25. Kinadjian, N, Le Bechec, M., Pigot, T., Dufour, F., Bentaleb, A., Prouzet, E., Lacombe, S., Backov, R., Eur. J. Inorg. Chem., 5350 (2012).

Keywords

Enzyme-based Biohybrid Foams Designed for Biodiesel Production and Continuous Flow Heterogeneous Catalysis

  • Nicolas Brun (a1), Hervé Deleuze (a2) and Rénal Backov (a1)

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed