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Electronic Properties Of The Model Organometallic Polymer [M-C=C(N)]n (M = Cu(I), Ag(I), Au(I))

Published online by Cambridge University Press:  10 February 2011

Z. M. Su ,
R. S. Wang  and
C. M. Che
Z. M. Su
Affiliation:
Institute of Functional Material Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024, P.R. China, zmsu@nenu edu cn
R. S. Wang
Affiliation:
Institute of Functional Material Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024, P.R. China, zmsu@nenu edu cn
C. M. Che
Affiliation:
Department of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong
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Abstract

The organometallic complexes of transition metal M = Cu(I), Ag(I), Au(I) with d10 electronic configuration have interesting optical, electronic and magnetic properties. It is possible to prepare the high functional organometallic polymer materials by coordinating π-conjugated organic molecules with d10 metals. According to the experimental structures, the model polymers [M-C-C(N)]n are built up and quantum chemistry methods are used to calculate their properties. It is indicated from theoretical analysis that the organometallic polymers would have comparable conductivity when interactions exist between metals and π electrons of different chains.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 576: Symposium DD – Organic/Inorganic Hybrid Materials II , 1999 , 389
Copyright
Copyright © Materials Research Society 1999

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References

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