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Electrical Conductivity Measurements of Leachates For The Rapid Assessment of Waste Form Corrosion Resistance*

Published online by Cambridge University Press:  21 February 2011

B. C. Sales ,
M. Petek  and
L. A. Boatner
B. C. Sales
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37830
M. Petek
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37830
L. A. Boatner
Affiliation:
Solid State Division, Oak Ridge National Laboratory, Oak Ridge, TN 37830
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Abstract

Measurements of the electrical conductivity of leachate solutions as a function of time can be used as an efficient, informative means of evaluation and comparison in the development of nuclear waste forms and in the preliminary analysis of their corrosion resistance in distilled water. Three separate applications of this technique are described in this work. These are: (1) its use in the optimization of the corrosion resistance of a crystalline wasteform (monazite); (2) a study of the protective ability of the surface layer (“gel layer”) which forms on the nuclear waste glass Frit 21 + 20 wt. % SRW in distilled water, and (3) making comparisons of the overall corrosion resistance of three different nuclear wasteforms (i.e., monazite, SYNROC, and borosilicate glass). A complete solution analysis of the borosilicate glass leachate and a straightforward analysis of the conductivity results agree to within ±20%. In the absence of a complete, time consuming solution analysis, conductivity measurements can be used to estimate reliably the total ionic concentration in the leachate to within a factor of 2.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 15: Symposium D – Scientific Basis for Nuclear Waste Management VI , 1982 , 251
Copyright
Copyright © Materials Research Society 1983

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Footnotes

*

Research sponsored by the Division of Materials Sciences, Office of Basic Energy Sciences, U.S. Department of Energy under contract W–7405–eng–26 with Union Carbide Corporation.

References

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